Five naphthalene-amide-bridged Ni(ii) complexes: electrochemistry, bifunctional fluorescence responses, removal of contaminants and optimization by CVD

doi:10.1039/c9ce01764j

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	Five naphthalene-amide-bridged Ni(ii) complexes: electrochemistry, bifunctional fluorescence responses, removal of contaminants and optimization by CVD
	Zhao, Jing 3; Luan, Jian 1; Yu, Huixuan 3; Liu, Guocheng 3; Lin, Hongyan 3; Wang, Xiuli 3; Chen, Baokuan 2
刊名	CRYSTENGCOMM
	2020-02-28
卷号	22 期号:8 页码:1330-1339
ISSN号	1466-8033
DOI	10.1039/c9ce01764j
通讯作者	Liu, Guocheng(lgch1004@sina.com) ; Wang, Xiuli(wangxiuli@bhu.edu.cn) ; Chen, Baokuan(chenbaokuan@lnpu.edu.cn)
英文摘要	To research the effect of carboxylates on the assembly of Ni(ii) coordination polymers, a naphthalene-amide ligand L (N,N '-bis(pyridin-3-ylmethyl)naphthalene-2,6-dicarboxamide) and five dicarboxylates [1,4-H2BDC = 1,4-benzenedicarboxylic acid, 1,4-H2PDC = 1,4-phenyldiacetic acid, 5-H2HIP = 5-hydroxyisophthalic acid, 3,4-H2TDC = 3,4-thiophenedicarboxylic acid, 2,5-H2TDC = 2,5-thiophenedicarboxylic acid] were selected to combine with Ni(ii) under hydrothermal conditions. Five coordination polymers [Ni(L)(1,4-BDC)(H2O)(2)] (1), [Ni(L)(1,4-PDC)(H2O)(2)] (2), [Ni(L)(5-HIP)(H2O)(2)] (3), [Ni(L)(3,4-TDC)(H2O)(2)]3H(2)O (4) and [Ni(L)(2,5-TDC)(H2O)](2)3H(2)O (5) were synthesized and structurally characterized by IR, PXRD and X-ray single-crystal diffraction. The title complexes show various structures: 2D 4-connected sql nets (1 and 2), a 3D cds framework of 3, 1D zigzag chain of 4 and 3D irl framework of 5. The electrochemical behaviors of 1-5 and the solid-state luminescence and fluorescence responses of 5 to Fe3+ and bovine serum albumin (BSA) were studied. Encouraged by functional thiophene components, 4 and 5 were used as catalyst precursors to synthesize carbon nanotubes (CNT-4 and CNT-5) by the chemical vapor deposition (CVD) method and characterized by XPS, SEM, TEM and Raman spectroscopy. The removals of contaminants (rhodamine B and Congo red) by 4 and 5 and their derivatives CNT-4 and CNT-5 in the aqueous phase were also comparatively investigated.
资助项目	National Natural Science Foundation of China[21401010] ; National Natural Science Foundation of China[21971024] ; National Natural Science Foundation of China[21671025] ; National Natural Science Foundation of China[21501078]
WOS研究方向	Chemistry ; Crystallography
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000524748400003
资助机构	National Natural Science Foundation of China
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/138186]
专题	金属研究所_中国科学院金属研究所
通讯作者	Liu, Guocheng; Wang, Xiuli; Chen, Baokuan
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Liaoning Shihua Univ, Coll Chem Chem Engn & Environm Engn, Fushun 113001, Peoples R China 3.Bohai Univ, Coll Chem & Chem Engn, Profess Technol Innovat Ctr Liaoning Prov Convers, Jinzhou 121013, Peoples R China
推荐引用方式 GB/T 7714	Zhao, Jing,Luan, Jian,Yu, Huixuan,et al. Five naphthalene-amide-bridged Ni(ii) complexes: electrochemistry, bifunctional fluorescence responses, removal of contaminants and optimization by CVD[J]. CRYSTENGCOMM,2020,22(8):1330-1339.
APA	Zhao, Jing.,Luan, Jian.,Yu, Huixuan.,Liu, Guocheng.,Lin, Hongyan.,...&Chen, Baokuan.(2020).Five naphthalene-amide-bridged Ni(ii) complexes: electrochemistry, bifunctional fluorescence responses, removal of contaminants and optimization by CVD.CRYSTENGCOMM,22(8),1330-1339.
MLA	Zhao, Jing,et al."Five naphthalene-amide-bridged Ni(ii) complexes: electrochemistry, bifunctional fluorescence responses, removal of contaminants and optimization by CVD".CRYSTENGCOMM 22.8(2020):1330-1339.