Plasma-assisted catalytic dry reforming of methane (DRM) over metal-organic frameworks (MOFs)-based catalysts

doi:10.1016/j.apcatb.2019.118195

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	Plasma-assisted catalytic dry reforming of methane (DRM) over metal-organic frameworks (MOFs)-based catalysts
	Vakili, Reza 2; Gholami, Rahman 2; Stere, Cristina E.2; Chansai, Sarayute 2; Chen, Huanhao 2; Holmes, Stuart M.2; Jiao, Yilai 1; Hardacre, Christopher 2; Fan, Xiaolei 2
刊名	APPLIED CATALYSIS B-ENVIRONMENTAL
	2020
卷号	260 页码:11
关键词	Non-thermal plasma Catalytic dry reforming of methane Metal-organic frameworks (MOFs) Dielectric barrier discharge (DBD) reactor In situ DRIFTS
ISSN号	0926-3373
DOI	10.1016/j.apcatb.2019.118195
通讯作者	Fan, Xiaolei(xiaolei.fan@manchester.ac.uk)
英文摘要	Plasma-assisted dry reforming of methane (DRM) was performed in a dielectric barrier discharge (DBD) reactor. The effect of different packing materials including ZrO2, UiO-67 MOF and PtNP@UiO-67 on plasma discharge was investigated, showing that ZrO2 suppressed the plasma generation while UiO-67 improves it due to its porous nature which favours the formation of filamentary microdischarges and surface discharges. The improved plasma discharge increased the conversion of CH4 and CO2 by about 18% and 10%, respectively, compared to the plasma-alone mode. In addition, the distribution of hydrocarbon products changed from dominant C2H6 in the plasma-alone mode to C2H2 and C2H4 in the UiO-67 promoted plasma-assisted DRM. The UiO-67 MOF was stable in plasma, showing no significant changes in its properties under different treatment times, discharge powers and gases. Pt nanoparticles (NPs) on UiO-67 improved plasma-assisted DRM, especially the selectivity due to the presence of surface reactions. Due to the dehydrogenation of hydrocarbons over Pt NPs, the selectivity to hydrocarbons decreased by 30%, compared to the UiO-67 packing. In situ diffuse reflectance infrared Fourier transformed spectroscopy (DRIFTS) was carried out to probe the surface reactions on PtNP@UiO-67 catalyst, showing the decomposition of surface formats to CO and C2H4 dehydrogenation over the metallic Pt. The PtNP@UiO-67 catalyst showed good reusability in the plasma-assisted DRM, and H-2 production was improved by high CH4/CO2 molar ratio and low feed flow rate.
资助项目	University of Manchester President's Doctoral Scholar Award ; European Commission Marie Sklodowska-Curie Individual Fellowship[748196]
WOS研究方向	Chemistry ; Engineering
语种	英语
出版者	ELSEVIER
WOS记录号	WOS:000496894300042
资助机构	University of Manchester President's Doctoral Scholar Award ; European Commission Marie Sklodowska-Curie Individual Fellowship
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/136877]
专题	金属研究所_中国科学院金属研究所
通讯作者	Fan, Xiaolei
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China 2.Univ Manchester, Sch Chem Engn & Analyt Sci, Oxford Rd, Manchester M13 9PL, Lancs, England
推荐引用方式 GB/T 7714	Vakili, Reza,Gholami, Rahman,Stere, Cristina E.,et al. Plasma-assisted catalytic dry reforming of methane (DRM) over metal-organic frameworks (MOFs)-based catalysts[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2020,260:11.
APA	Vakili, Reza.,Gholami, Rahman.,Stere, Cristina E..,Chansai, Sarayute.,Chen, Huanhao.,...&Fan, Xiaolei.(2020).Plasma-assisted catalytic dry reforming of methane (DRM) over metal-organic frameworks (MOFs)-based catalysts.APPLIED CATALYSIS B-ENVIRONMENTAL,260,11.
MLA	Vakili, Reza,et al."Plasma-assisted catalytic dry reforming of methane (DRM) over metal-organic frameworks (MOFs)-based catalysts".APPLIED CATALYSIS B-ENVIRONMENTAL 260(2020):11.