Factors of Kinetics Processes in Lithium-Sulfur Reactions | |
Tang, Xiaonan1,2; Xu, Zichen2; Sun, Zhenhua1,3; Zhou, Jin2; Wu, Xiaozhong2; Lin, Hongtao2; Rong, Junfeng4; Zhuo, Shuping2; Li, Feng1,3 | |
刊名 | ENERGY TECHNOLOGY |
2019-09-26 | |
页码 | 17 |
关键词 | cell design electrode structures kinetics process lithium-sulfur batteries sulfur host materials |
ISSN号 | 2194-4288 |
DOI | 10.1002/ente.201900574 |
通讯作者 | Zhuo, Shuping(zhuosp_academic@yahoo.com) ; Li, Feng(fli@imr.ac.cn) |
英文摘要 | Lithium-Sulfur (Li-S) batteries are among the most promising next-generation secondary battery technologies due to their high theoretical energy density. However, the Li-S reaction is a multistep process and a solid-liquid-solid phase transition process, relating to complex reaction kinetics. Moreover, the poor conductivity of sulfur hinders effective electron transport, and large volume expansion leads to electrode pulverization, causing the electrode to lose effective electrical contact, which decreases the kinetics. In this review, the factors influencing kinetics processes in Li-S electrochemistry are reviewed, starting from the design of sulfur host materials, along with electrode structure. Then, the cell design including electrolyte, interlayer, etc., is discussed further. Finally, insights on how to improve the kinetics are provided, which is expected to provide direction for further kinetic investigation of Li-S batteries. |
资助项目 | National Key R&D Program of China[2016YFB0100100] ; National Key R&D Program of China[2016YFA0200100] ; National Natural Science Foundation of China[51525206] ; National Natural Science Foundation of China[21576159] ; National Natural Science Foundation of China[21576158] ; National Natural Science Foundation of China[51521091] ; National Natural Science Foundation of China[51972313] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDA22010602] ; Youth Innovation Promotion Association of the Chinese Academy of Sciences[2015150] ; Natural Science Foundation of Shandong Province[ZR2017JL014] ; China Petrochemical Cooperation[218025] |
WOS研究方向 | Energy & Fuels |
语种 | 英语 |
出版者 | WILEY-V C H VERLAG GMBH |
WOS记录号 | WOS:000487781800001 |
资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; Natural Science Foundation of Shandong Province ; China Petrochemical Cooperation |
内容类型 | 期刊论文 |
源URL | [http://ir.imr.ac.cn/handle/321006/135476] |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Zhuo, Shuping; Li, Feng |
作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 2.Shandong Univ Technol, Sch Chem Engn, Zibo 255049, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China 4.Sinopec, Res Inst Petr Proc, Beijing 100083, Peoples R China |
推荐引用方式 GB/T 7714 | Tang, Xiaonan,Xu, Zichen,Sun, Zhenhua,et al. Factors of Kinetics Processes in Lithium-Sulfur Reactions[J]. ENERGY TECHNOLOGY,2019:17. |
APA | Tang, Xiaonan.,Xu, Zichen.,Sun, Zhenhua.,Zhou, Jin.,Wu, Xiaozhong.,...&Li, Feng.(2019).Factors of Kinetics Processes in Lithium-Sulfur Reactions.ENERGY TECHNOLOGY,17. |
MLA | Tang, Xiaonan,et al."Factors of Kinetics Processes in Lithium-Sulfur Reactions".ENERGY TECHNOLOGY (2019):17. |
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