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Effects of reduced sulfur on passive film properties of steam generator (SG) tubing: an overview
Xia, Da-Hai1,2,3; Luo, Jing-Li2
刊名ANTI-CORROSION METHODS AND MATERIALS
2019-05-07
卷号66期号:3页码:317-326
关键词Corrosion Passive film Steam generator Sulphide Tetrathionate Thiosulphate
ISSN号0003-5599
DOI10.1108/ACMM-09-2018-1996
通讯作者Xia, Da-Hai(dahaixia@tju.edu.cn) ; Luo, Jing-Li(jingli_luo@ualberta.ca)
英文摘要Purpose Corrosion is considered as one of the issues that threaten the safe operation of steam generator (SG) tubing. Some sulfur-related specie can cause corrosion degradation of SG tubing. Sulfur-induced corrosion of SG alloys in high temperature and high-pressure water is one of the most complicated processes. The purpose of this study is to study the effect of reduced sulphur on passive film properties of steam generator (SG) tubing. Design/methodology/approach In this paper, the effects of reduced sulfur on passive film properties of SG tubing were reviewed from the aspects of thermodynamic calculations and experimental. Findings Thermodynamic calculations are mainly presented by E-pH diagrams, volt equivalent diagrams and species distribution curves. The stability of sulphur species highly depends on temperature, solution pH, and electrochemical potential. Experimental data indicated that reduced sulfur species can interact with the passive film, which led to changes in film thickness, film structure, semiconductivity and pitting growth rate. Originality/value The state-of-the-art discussed in this paper gives basis for resolving engineering problems regarding with sulfur-induced corrosion.
资助项目National Natural Science Foundation of China[51701140] ; open-ended fund of the CAS Key laboratory of Nuclear Materials and Safety Assessment (Institute of Metal Research, Chinese Academy of Sciences, China)[2018NMSAKF01]
WOS研究方向Metallurgy & Metallurgical Engineering
语种英语
出版者EMERALD GROUP PUBLISHING LTD
WOS记录号WOS:000465588100007
资助机构National Natural Science Foundation of China ; open-ended fund of the CAS Key laboratory of Nuclear Materials and Safety Assessment (Institute of Metal Research, Chinese Academy of Sciences, China)
内容类型期刊论文
源URL[http://ir.imr.ac.cn/handle/321006/133034]  
专题金属研究所_中国科学院金属研究所
通讯作者Xia, Da-Hai; Luo, Jing-Li
作者单位1.Tianjin Univ, Tianjin Key Lab Composite & Funct Mat, Sch Mat Sci & Engn, Tianjin, Peoples R China
2.Univ Alberta, Dept Chem & Mat Engn, Edmonton, AB, Canada
3.Chinese Acad Sci, Inst Met Res, Shenyang, Liaoning, Peoples R China
推荐引用方式
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Xia, Da-Hai,Luo, Jing-Li. Effects of reduced sulfur on passive film properties of steam generator (SG) tubing: an overview[J]. ANTI-CORROSION METHODS AND MATERIALS,2019,66(3):317-326.
APA Xia, Da-Hai,&Luo, Jing-Li.(2019).Effects of reduced sulfur on passive film properties of steam generator (SG) tubing: an overview.ANTI-CORROSION METHODS AND MATERIALS,66(3),317-326.
MLA Xia, Da-Hai,et al."Effects of reduced sulfur on passive film properties of steam generator (SG) tubing: an overview".ANTI-CORROSION METHODS AND MATERIALS 66.3(2019):317-326.
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