Palladium nanoclusters immobilized on defective nanodiamond-graphene core-shell supports for semihydrogenation of phenylacetylene

doi:10.1016/j.jechem.2018.08.006

CORC > 金属研究所 > 中国科学院金属研究所

	Palladium nanoclusters immobilized on defective nanodiamond-graphene core-shell supports for semihydrogenation of phenylacetylene
	Huang, Fei 1,2; Jia, Zhimin 1,2; Diao, Jiangyong 2; Yuan, Hua 3; Su, Dangsheng 2; Liu, Hongyang 2
刊名	JOURNAL OF ENERGY CHEMISTRY
	2019-06-01
卷号	33 页码:31-36
关键词	Selective hydrogenation Palladium nanoclusters Nanocarbon support Liquid-phase hydrogenation
ISSN号	2095-4956
DOI	10.1016/j.jechem.2018.08.006
通讯作者	Liu, Hongyang(liuhy@imr.ac.cn)
英文摘要	We report a nanocarbon material with nanodiamond (ND) core and graphene shell (ND@G) as a support for Pd nanocatalysts. The designed catalyst performed good selectivity of styrene (85.2%) at full conversion of phenylacetylene and superior stability under mild conditions. Supported Pd catalysts are characterized by means of high resolution transmission electron microscopy (HRTEM), Raman, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and H-2 temperature-programmed reduction (H-2-TPR). The results clearly show that formation of the strong metal-support interaction (SMSI) between Pd nanoclusters and the defective graphene shell helpfully modifies the selectivity and stability of the Pd-based catalysts. (C) 2018 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
资助项目	Ministry of Science and Technology[2016YFA0204100] ; National Natural Science Foundation of China[21573254] ; National Natural Science Foundation of China[21703261] ; National Natural Science Foundation of China[91545110] ; Youth Innovation Promotion Association (CAS) ; Sinopec China[XDA09030103] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA09030103] ; Chongqing Research Program of Basic Research and Frontier Technology[cstc2016jcyjA0432] ; Scientific and Technological Research Program of Chongqing Municipal Education Commission[KJ1600328]
WOS研究方向	Chemistry ; Energy & Fuels ; Engineering
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000457881000005
资助机构	Ministry of Science and Technology ; National Natural Science Foundation of China ; Youth Innovation Promotion Association (CAS) ; Sinopec China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Chongqing Research Program of Basic Research and Frontier Technology ; Scientific and Technological Research Program of Chongqing Municipal Education Commission
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/131521]
专题	金属研究所_中国科学院金属研究所
通讯作者	Liu, Hongyang
作者单位	1.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Anhui, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 3.Chongqing Normal Univ, Coll Chem, Chongqing 401331, Peoples R China
推荐引用方式 GB/T 7714	Huang, Fei,Jia, Zhimin,Diao, Jiangyong,et al. Palladium nanoclusters immobilized on defective nanodiamond-graphene core-shell supports for semihydrogenation of phenylacetylene[J]. JOURNAL OF ENERGY CHEMISTRY,2019,33:31-36.
APA	Huang, Fei,Jia, Zhimin,Diao, Jiangyong,Yuan, Hua,Su, Dangsheng,&Liu, Hongyang.(2019).Palladium nanoclusters immobilized on defective nanodiamond-graphene core-shell supports for semihydrogenation of phenylacetylene.JOURNAL OF ENERGY CHEMISTRY,33,31-36.
MLA	Huang, Fei,et al."Palladium nanoclusters immobilized on defective nanodiamond-graphene core-shell supports for semihydrogenation of phenylacetylene".JOURNAL OF ENERGY CHEMISTRY 33(2019):31-36.