Effects of the addition of Co, Ni or Cr on the decolorization properties of Fe-Si-B amorphous alloys

doi:10.1016/j.jpcs.2017.06.010

CORC > 金属研究所 > 中国科学院金属研究所

	Effects of the addition of Co, Ni or Cr on the decolorization properties of Fe-Si-B amorphous alloys
	Zhang, Changqin 1; Zhu, Zhengwang 2; Zhang, Haifeng 2
刊名	JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
	2017-11-01
卷号	110 页码:152-160
关键词	Fe-based amorphous alloys Surface structures Decolorization properties Azo dyes
ISSN号	0022-3697
DOI	10.1016/j.jpcs.2017.06.010
通讯作者	Zhang, Changqin(zhangcq@alum.imr.ac.cn)
英文摘要	Fe-based amorphoui alloys show great potential in degrading azo dyes and other organic pollutants, and are widely investigated as a kind of environmental-friendly materials for wastewater remediation. In this paper, the effects of Co, Ni or Cr addition on the decolorization properties of Fe-Si-B amorphous alloys were studied, and the mechanism of their different effects was analyzed. Co addition could lower the activation energy of Fe-Si-B amorphous alloys in decolorizing azo dyes, and had no weakening effect on the decolorization capability of Fe-Si-B amorphous alloys. Ni addition led to partial crystallization of Fe-Si-B amorphous alloys, and the decolorization mechanism at low temperatures changed from chemical degradation to physical adsorption. Cr addition could enhance the corrosion resistance of Fe-Si-B amorphous alloys, but the amorphous alloys completely lost the decolorization capability no matter at lower or higher temperatures. The results of X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) indicated that the addition of Co, Ni or Cr could generate different surface structures that had significant influences on the decolorization process. Our work demonstrated that the effiecient decolorization of azo dyes by Fe-based alloys could be realized only when amorphous nature and incompact surface structure were simultaneously achieved for the alloys.
资助项目	Doctor Fund of Shandong Jianzhu University[XNBS1429]
WOS研究方向	Chemistry ; Physics
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000407660700019
资助机构	Doctor Fund of Shandong Jianzhu University
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/125037]
专题	金属研究所_中国科学院金属研究所
通讯作者	Zhang, Changqin
作者单位	1.Shandong Jianzhu Univ, Sch Mat Sci & Engn, Jinan 250101, Shandong, Peoples R China 2.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Changqin,Zhu, Zhengwang,Zhang, Haifeng. Effects of the addition of Co, Ni or Cr on the decolorization properties of Fe-Si-B amorphous alloys[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS,2017,110:152-160.
APA	Zhang, Changqin,Zhu, Zhengwang,&Zhang, Haifeng.(2017).Effects of the addition of Co, Ni or Cr on the decolorization properties of Fe-Si-B amorphous alloys.JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS,110,152-160.
MLA	Zhang, Changqin,et al."Effects of the addition of Co, Ni or Cr on the decolorization properties of Fe-Si-B amorphous alloys".JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS 110(2017):152-160.