Preparation of particle electrodes from manganese slag and its degradation performance for salicylic acid in the three-dimensional electrode reactor (TDE)

CORC > 生态环境研究中心 > 中国科学院生态环境研究中心 > 环境水质学国家重点实验室

	Preparation of particle electrodes from manganese slag and its degradation performance for salicylic acid in the three-dimensional electrode reactor (TDE)
	Chen, Hao ; Feng, Yan ; Suo, Ning ; Long, Yingying ; Li, Xue ; Shi, Yulong ; Yu, Yanzhen
刊名	CHEMOSPHERE
	2019-02
卷号	216 页码:281-288
关键词	Salicylic acid The three-dimensional electrode reactor Manganese slag Impact factor Degradation pathway
ISSN号	0045-6535
英文摘要	Salicylic acid (SA) is a class of trace pollutants widely presented in the environment belonged to pharmaceuticals and personal care products. It is difficult to remove SA by the traditional treatment processes because of its toxicity. In this paper, the degradation of SA by Mn-loaded Cu/Fe particle electrodes was studied. Firstly, the particle electrodes were prepared by impregnation-roasting method and then characterized by SEM, XRF and XRD. The diffraction peaks of Fe2O3 and CuO in the XRD patterns of the particle electrodes which had the dense spherical particles were significantly increased and the content of CuO and Fe2O3 increased by 1.9% and 3.6% respectively. Secondly, single factor experiments were carried out under conditions of cell voltage, electrolyte concentration, pH, HRT, inter-electrode distance and initial pollutant concentration. Under the optimum conditions of all the factors, the degradation rate of SA reached 76.9%. Then, HPLC and GCMS were employed to deduce the degradation pathways of SA by the TDE with Mn-particle electrodes (Mn-PETDE). Under the action of center dot OH, SA underwent decarboxylation and substitution reactions and then mineralized after the ring-opening reaction. All results demonstrated that this Mn-PETDE was effective for degradation of SA. (C) 2018 Elsevier Ltd. All rights reserved.
内容类型	期刊论文
源URL	[http://ir.rcees.ac.cn/handle/311016/43108]
专题	生态环境研究中心_环境水质学国家重点实验室
作者单位	1.Harbin Inst Technol, Sch Municipal & Environm Engn, Harbin 150090, Heilongjiang, Peoples R China 2.Chinese Acad Sci, State Key Lab Environm Aquat Chem, Res Ctr Ecoenvironm Sci, Beijing 100085, Peoples R China 3.Beijing Drainage Grp Co Ltd, Ctr Res & Dev, Beijing 100124, Peoples R China 4.Univ Jinan, Sch Civil Engn & Architecture, Jinan 250022, Shandong, Peoples R China 5.Qilu Inst Technol, Sch Civil Engn & Architecture, Jinan 250022, Shandong, Peoples R China
推荐引用方式 GB/T 7714	Chen, Hao,Feng, Yan,Suo, Ning,et al. Preparation of particle electrodes from manganese slag and its degradation performance for salicylic acid in the three-dimensional electrode reactor (TDE)[J]. CHEMOSPHERE,2019,216:281-288.
APA	Chen, Hao.,Feng, Yan.,Suo, Ning.,Long, Yingying.,Li, Xue.,...&Yu, Yanzhen.(2019).Preparation of particle electrodes from manganese slag and its degradation performance for salicylic acid in the three-dimensional electrode reactor (TDE).CHEMOSPHERE,216,281-288.
MLA	Chen, Hao,et al."Preparation of particle electrodes from manganese slag and its degradation performance for salicylic acid in the three-dimensional electrode reactor (TDE)".CHEMOSPHERE 216(2019):281-288.