Catalytic self-etherification of 5-hydroxymethylfurfural to 5,5 '(oxy-bis(methylene))bis-2-furfural over zeolite catalysts: effect of pore structure and acidity
Zhang, Pilan; Yang, Jie; Hu, Hualei; Hu, Danxin; Gan, Jiang; Zhang, Yexin; Chen, Chunlin; Li, Xiaoqiang; Wang, Lei; Zhang, Jian
刊名CATALYSIS SCIENCE & TECHNOLOGY
2020
卷号10期号:14页码:4684-4692
关键词EFFICIENT PRODUCTION BENZENE ALKYLATION FURANIC DIETHER BIOMASS 2,5-BIS(HYDROXYMETHYL)FURAN HYDROGENATION PERFORMANCE SELECTIVITY FRUCTOSE METHANOL
DOI10.1039/d0cy00733a
英文摘要The self-etherification of 5-hydroxymethylfurfural (HMF) to 5,5 '(oxy-bis(methylene))bis-2-furfural (OBMF) was investigated on ZSM-5, MCM-22, beta and hierarchical micro-mesoporous ZSM-5 (HMZ) catalysts. The hierarchically structured zeolites exhibited a superior intrinsic activity and good resistance to carbonaceous deposit; the latter could be ascribed to the lower mass transfer barrier in the mesopores of the HMZ catalysts. The structure-activity correlation showed that the catalytic activity mainly originated from one or several specific Bronsted acid sites, providing key clues to design efficient zeolite catalysts for producing OBMF.
学科主题Chemistry
内容类型期刊论文
源URL[http://ir.nimte.ac.cn/handle/174433/20639]  
专题2020专题
作者单位1.Zhang, J (corresponding author), Univ Chinese Acad Sci, Beijing 100049, Peoples R China.
2.Zhang, J (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, 1219 Zhongguan West Rd, Ningbo 315201, Peoples R China.
3.Wang, L (corresponding author), Zhejiang Sugar Energy Technol Co Ltd, 1818 Zhongguan West Rd, Ningbo 315201, Peoples R China.
4.Hu, HL
5.Wang, L
推荐引用方式
GB/T 7714
Zhang, Pilan,Yang, Jie,Hu, Hualei,et al. Catalytic self-etherification of 5-hydroxymethylfurfural to 5,5 '(oxy-bis(methylene))bis-2-furfural over zeolite catalysts: effect of pore structure and acidity[J]. CATALYSIS SCIENCE & TECHNOLOGY,2020,10(14):4684-4692.
APA Zhang, Pilan.,Yang, Jie.,Hu, Hualei.,Hu, Danxin.,Gan, Jiang.,...&Zhang, Jian.(2020).Catalytic self-etherification of 5-hydroxymethylfurfural to 5,5 '(oxy-bis(methylene))bis-2-furfural over zeolite catalysts: effect of pore structure and acidity.CATALYSIS SCIENCE & TECHNOLOGY,10(14),4684-4692.
MLA Zhang, Pilan,et al."Catalytic self-etherification of 5-hydroxymethylfurfural to 5,5 '(oxy-bis(methylene))bis-2-furfural over zeolite catalysts: effect of pore structure and acidity".CATALYSIS SCIENCE & TECHNOLOGY 10.14(2020):4684-4692.
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