Catalytic self-etherification of 5-hydroxymethylfurfural to 5,5 '(oxy-bis(methylene))bis-2-furfural over zeolite catalysts: effect of pore structure and acidity | |
Zhang, Pilan; Yang, Jie; Hu, Hualei; Hu, Danxin; Gan, Jiang; Zhang, Yexin; Chen, Chunlin; Li, Xiaoqiang; Wang, Lei; Zhang, Jian | |
刊名 | CATALYSIS SCIENCE & TECHNOLOGY |
2020 | |
卷号 | 10期号:14页码:4684-4692 |
关键词 | EFFICIENT PRODUCTION BENZENE ALKYLATION FURANIC DIETHER BIOMASS 2,5-BIS(HYDROXYMETHYL)FURAN HYDROGENATION PERFORMANCE SELECTIVITY FRUCTOSE METHANOL |
DOI | 10.1039/d0cy00733a |
英文摘要 | The self-etherification of 5-hydroxymethylfurfural (HMF) to 5,5 '(oxy-bis(methylene))bis-2-furfural (OBMF) was investigated on ZSM-5, MCM-22, beta and hierarchical micro-mesoporous ZSM-5 (HMZ) catalysts. The hierarchically structured zeolites exhibited a superior intrinsic activity and good resistance to carbonaceous deposit; the latter could be ascribed to the lower mass transfer barrier in the mesopores of the HMZ catalysts. The structure-activity correlation showed that the catalytic activity mainly originated from one or several specific Bronsted acid sites, providing key clues to design efficient zeolite catalysts for producing OBMF. |
学科主题 | Chemistry |
内容类型 | 期刊论文 |
源URL | [http://ir.nimte.ac.cn/handle/174433/20639] |
专题 | 2020专题 |
作者单位 | 1.Zhang, J (corresponding author), Univ Chinese Acad Sci, Beijing 100049, Peoples R China. 2.Zhang, J (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, 1219 Zhongguan West Rd, Ningbo 315201, Peoples R China. 3.Wang, L (corresponding author), Zhejiang Sugar Energy Technol Co Ltd, 1818 Zhongguan West Rd, Ningbo 315201, Peoples R China. 4.Hu, HL 5.Wang, L |
推荐引用方式 GB/T 7714 | Zhang, Pilan,Yang, Jie,Hu, Hualei,et al. Catalytic self-etherification of 5-hydroxymethylfurfural to 5,5 '(oxy-bis(methylene))bis-2-furfural over zeolite catalysts: effect of pore structure and acidity[J]. CATALYSIS SCIENCE & TECHNOLOGY,2020,10(14):4684-4692. |
APA | Zhang, Pilan.,Yang, Jie.,Hu, Hualei.,Hu, Danxin.,Gan, Jiang.,...&Zhang, Jian.(2020).Catalytic self-etherification of 5-hydroxymethylfurfural to 5,5 '(oxy-bis(methylene))bis-2-furfural over zeolite catalysts: effect of pore structure and acidity.CATALYSIS SCIENCE & TECHNOLOGY,10(14),4684-4692. |
MLA | Zhang, Pilan,et al."Catalytic self-etherification of 5-hydroxymethylfurfural to 5,5 '(oxy-bis(methylene))bis-2-furfural over zeolite catalysts: effect of pore structure and acidity".CATALYSIS SCIENCE & TECHNOLOGY 10.14(2020):4684-4692. |
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