Template Preparation of Copper-Based Chalcogenides and their Electrochemical Performance for Li-ion Batteries
Chen, Yanfen; Pei, Quan; Liu, Xiaolin; Chen, Xiuli; Rao, Xianfa; Li, Dong; Chen, Guoxin; Zhong, Shengwen
刊名CHEMISTRYSELECT
2020
卷号5期号:42页码:12873-12877
关键词CUO NANOPARTICLES MECHANISM ANODE CARBON CUSE
DOI10.1002/slct.202003227
英文摘要Transition-Metal chalcogenides have high Li-ion storage capacity and considerable cycle performance, which has attracted great interest from researchers and is expected to replace graphite materials in the field of Li ion batteries. The purpose of this paper is to find a low-cost and ecofriendly method for producing copper-based chalcogenides as anodes with a high capacity and long cycling stability for lithium ion batteries. In our strategy, carbon nanospheres are used as templates to prepare precursor Cu(OH)(2)@C. Then, the Cu(OH)(2)@C is converted into copper-based chalcogenides by different routes. The structure and morphology of the as-synthesized materials is characterized by the X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The anode electrochemical performance of the samples was investigated by galvanostatic cycling (GC) vs. Li/Li+ at different current rate. Compared to other copper chalcogenides, the synthesized copper oxide shows better charge/discharge cycle stability and rate performance. Its capacity retention is as high as 128 % at a current density of 0.5 C after 200 cycles.
学科主题Chemistry
内容类型期刊论文
源URL[http://ir.nimte.ac.cn/handle/174433/20350]  
专题2020专题
作者单位1.Liu, XL
2.Zhong, SW (corresponding author), Jiangxi Univ Sci & Technol, Sch Mat Sci & Engn, Key Lab Power Batteries & Mat, Ganzhou 341000, Jiangxi, Peoples R China.
推荐引用方式
GB/T 7714
Chen, Yanfen,Pei, Quan,Liu, Xiaolin,et al. Template Preparation of Copper-Based Chalcogenides and their Electrochemical Performance for Li-ion Batteries[J]. CHEMISTRYSELECT,2020,5(42):12873-12877.
APA Chen, Yanfen.,Pei, Quan.,Liu, Xiaolin.,Chen, Xiuli.,Rao, Xianfa.,...&Zhong, Shengwen.(2020).Template Preparation of Copper-Based Chalcogenides and their Electrochemical Performance for Li-ion Batteries.CHEMISTRYSELECT,5(42),12873-12877.
MLA Chen, Yanfen,et al."Template Preparation of Copper-Based Chalcogenides and their Electrochemical Performance for Li-ion Batteries".CHEMISTRYSELECT 5.42(2020):12873-12877.
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