Building hierarchical zeolite structure by post-synthesis treatment to promote the conversion of furanic molecules into biofuels
Hu, Danxin; Hu Hualei; Jin, Haitao; Zhang, Pilan; Hu, Yunhan; Ying, Suhua; Li, Xianming; Yang, Yong; Zhang, Jian; Wang, Lei
刊名APPLIED CATALYSIS A-GENERAL
2020
卷号590
关键词CATALYTIC TRANSFORMATION EFFICIENT PRODUCTION BENZENE ALKYLATION ZSM-5 ZEOLITES ETHERIFICATION DESILICATION LEWIS MFI PERFORMANCE PLATFORM
DOI10.1016/j.apcata.2019.117338
英文摘要The highly selective conversion of furanic molecules to biofuels was achieved on the hierarchical catalysts, which were prepared through modifying the commercially microporous zeolites with sequential alkali and acid post-synthesis treatments. The characterization results indicated that the post-synthesis treatment could successfully introduce the mesopores into the microporous ZSM-5 sample as well as adjust its acidity. The yield of three furanic ethers i.e. 2,5-bis(ethoxymethyl)furan, 5-ethoxymethyl-furfural, and ethyl furfuryl ether on the AT(0.50)-OT catalyst were 94.7%, 90.6%, and 58.2%, respectively. The excellent performance could be attributed to the synergic effect of mass transfer efficiency and surface acidity. This work provides a simple route to prepare high-performance catalysts for the production of biofuels from biochemical.
学科主题Chemistry ; Environmental Sciences & Ecology
内容类型期刊论文
源URL[http://ir.nimte.ac.cn/handle/174433/20136]  
专题2020专题
作者单位1.Hu, HL
2.Zhang, J
3.Wang, L (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, 1219 Zhongguan West Rd, Ningbo 315201, Peoples R China.
推荐引用方式
GB/T 7714
Hu, Danxin,Hu Hualei,Jin, Haitao,et al. Building hierarchical zeolite structure by post-synthesis treatment to promote the conversion of furanic molecules into biofuels[J]. APPLIED CATALYSIS A-GENERAL,2020,590.
APA Hu, Danxin.,Hu Hualei.,Jin, Haitao.,Zhang, Pilan.,Hu, Yunhan.,...&Wang, Lei.(2020).Building hierarchical zeolite structure by post-synthesis treatment to promote the conversion of furanic molecules into biofuels.APPLIED CATALYSIS A-GENERAL,590.
MLA Hu, Danxin,et al."Building hierarchical zeolite structure by post-synthesis treatment to promote the conversion of furanic molecules into biofuels".APPLIED CATALYSIS A-GENERAL 590(2020).
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