Liquid-like secondary amine containing POSS as reactive nanoadditive to improve the anticorrosion performance of epoxy coating
Chen, Bin; Jin, Zhengyu; Pei, Xinpeng; Li, Jingyu; Liu, Chengbao; Zhao, Haichao
刊名MATERIALS LETTERS
2020
卷号261
关键词POLYMERS COPOLYMERS
DOI10.1016/j.matlet.2019.127103
英文摘要The octaaminopropyl polyhedral oligomeric silsesquioxane (OapPOSS) was firstly synthesized through hydrolytic condensation of 3-aminopropyltriethoxysilane. Then, the secondary amine containing POSS was prepared by Michael addition reaction of OapPOSS and diethyl maleate. The resulting hybrid nanomaterial is a viscous liquid that can be uniformly dispersed in the epoxy resin as a reactive component. Results of electrochemical impedance spectroscopy indicated that functionalized POSS significantly enhanced the anticorrosion performance of epoxy coatings. The POSS, acts as a cross-linkage, improved the crosslink density of resin matrix and enhanced the impermeability of composite coatings. (C) 2019 Elsevier B.V. All rights reserved.
学科主题Materials Science ; Physics
内容类型期刊论文
源URL[http://ir.nimte.ac.cn/handle/174433/19970]  
专题2020专题
作者单位1.Zhao, HC (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Marine Mat & Technol, Zhejiang Key Lab Marine Mat & Protect Technol, Ningbo 315201, Peoples R China.
2.Chen, B (corresponding author), Shenyang Univ Chem Technol, Sch Mat Sci & Engn, Shenyang 110142, Peoples R China.
推荐引用方式
GB/T 7714
Chen, Bin,Jin, Zhengyu,Pei, Xinpeng,et al. Liquid-like secondary amine containing POSS as reactive nanoadditive to improve the anticorrosion performance of epoxy coating[J]. MATERIALS LETTERS,2020,261.
APA Chen, Bin,Jin, Zhengyu,Pei, Xinpeng,Li, Jingyu,Liu, Chengbao,&Zhao, Haichao.(2020).Liquid-like secondary amine containing POSS as reactive nanoadditive to improve the anticorrosion performance of epoxy coating.MATERIALS LETTERS,261.
MLA Chen, Bin,et al."Liquid-like secondary amine containing POSS as reactive nanoadditive to improve the anticorrosion performance of epoxy coating".MATERIALS LETTERS 261(2020).
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