Inheritance from glass to liquid: beta relaxation depresses the nucleation of crystals
Song, L. J.; Gao, M.; Xu, W.; Huo, J. T.; Wang, J. Q.; Li, R. W.; Wang, W. H.; Perepezko, J. H.
刊名ACTA MATERIALIA
2020
卷号185页码:38-44
关键词METALLIC GLASSES FORMING METALS CRYSTALLIZATION GROWTH
DOI10.1016/j.actamat.2019.12.002
英文摘要Both crystallization and relaxation are intrinsic characteristics that derive from the metastable nature of metallic glasses. However, the interactions between the two reactions are not understood fully. In this paper, enthalpy evolution and phase existence diagrams composed of liquid, glass and crystal are established to illustrate the phase transitions upon heating and cooling a metallic glass-forming material. We find that metallic glasses located in different enthalpy levels in the diagrams exhibit quite different resistance to crystallization. The crystal nucleation rate for the fast-cooled glass is smaller compared to the slow-cooled glass, which is verified to be correlated with the larger amount of beta relaxation in the fast-cooled sample. These findings provide new evidence for the inheritance between glass and liquid, and suggest that modulating the glassy state is a new route to control the crystallization kinetics of supercooled liquids. (C) 2019 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
学科主题Materials Science ; Metallurgy & Metallurgical Engineering
内容类型期刊论文
源URL[http://ir.nimte.ac.cn/handle/174433/19968]  
专题2020专题
作者单位1.Huo, JT
2.Wang, JQ (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Zhejiang Prov Key Lab Magnet Mat & Applicat Techn, Ningbo 315201, Peoples R China.
3.Wang, JQ (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Magnet Mat & Devices, Ningbo 315201, Peoples R China.
推荐引用方式
GB/T 7714
Song, L. J.,Gao, M.,Xu, W.,et al. Inheritance from glass to liquid: beta relaxation depresses the nucleation of crystals[J]. ACTA MATERIALIA,2020,185:38-44.
APA Song, L. J..,Gao, M..,Xu, W..,Huo, J. T..,Wang, J. Q..,...&Perepezko, J. H..(2020).Inheritance from glass to liquid: beta relaxation depresses the nucleation of crystals.ACTA MATERIALIA,185,38-44.
MLA Song, L. J.,et al."Inheritance from glass to liquid: beta relaxation depresses the nucleation of crystals".ACTA MATERIALIA 185(2020):38-44.
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