Hydrate dissociation conditions for gas mixtures containing carbon dioxide, hydrogen, hydrogen sulfide, nitrogen, and hydrocarbons using SAFT
Li, Xiao-Sen; Wu, Hui-Jie; Li, Yi-Gui; Feng, Zi-Ping; Tang, Liang-Guang; Fan, Shuan-Shi
刊名journal of chemical thermodynamics
2007-03-01
卷号39期号:3页码:417-425
关键词hydrate SAFT equation of state phase equilibria gas mixture
ISSN号0021-9614
通讯作者lixs@ms.giec.ac.cn
中文摘要a new method, a molecular thermodynamic model based on statistical mechanics, is employed to predict the hydrate dissociation conditions for binary gas mixtures with carbon dioxide, hydrogen, hydrogen sulfide, nitrogen, and hydrocarbons in the presence of aqueous solutions. the statistical associating fluid theory (saft) equation of state is employed to characterize the vapor and liquid phases and the statistical model of van der waals and platteeuw for the hydrate phase. the predictions of the proposed model were found to be in satisfactory to excellent agreement with the experimental data.
英文摘要a new method, a molecular thermodynamic model based on statistical mechanics, is employed to predict the hydrate dissociation conditions for binary gas mixtures with carbon dioxide, hydrogen, hydrogen sulfide, nitrogen, and hydrocarbons in the presence of aqueous solutions. the statistical associating fluid theory (saft) equation of state is employed to characterize the vapor and liquid phases and the statistical model of van der waals and platteeuw for the hydrate phase. the predictions of the proposed model were found to be in satisfactory to excellent agreement with the experimental data. (c) 2006 elsevier ltd. all rights reserved.
WOS标题词science & technology ; physical sciences
类目[WOS]thermodynamics ; chemistry, physical
研究领域[WOS]thermodynamics ; chemistry
关键词[WOS]equation-of-state ; thermodynamic perturbation-theory ; vapor-liquid-equilibrium ; trebble-bishnoi equation ; associating fluids ; phase-equilibria ; prediction ; methanol ; systems ; water
收录类别SCI
原文出处http://www.sciencedirect.com/science/journal/00219614
语种英语
WOS记录号WOS:000244649100007
公开日期2010-09-27
内容类型期刊论文
源URL[http://ir.giec.ac.cn/handle/344007/3488]  
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Inst Energy Convers, Guangzhou 510640, Peoples R China
2.Tsinghua Univ, Dept Chem Engn, State Key Lab Chem Engn, Beijing 100084, Peoples R China
推荐引用方式
GB/T 7714
Li, Xiao-Sen,Wu, Hui-Jie,Li, Yi-Gui,et al. Hydrate dissociation conditions for gas mixtures containing carbon dioxide, hydrogen, hydrogen sulfide, nitrogen, and hydrocarbons using SAFT[J]. journal of chemical thermodynamics,2007,39(3):417-425.
APA Li, Xiao-Sen,Wu, Hui-Jie,Li, Yi-Gui,Feng, Zi-Ping,Tang, Liang-Guang,&Fan, Shuan-Shi.(2007).Hydrate dissociation conditions for gas mixtures containing carbon dioxide, hydrogen, hydrogen sulfide, nitrogen, and hydrocarbons using SAFT.journal of chemical thermodynamics,39(3),417-425.
MLA Li, Xiao-Sen,et al."Hydrate dissociation conditions for gas mixtures containing carbon dioxide, hydrogen, hydrogen sulfide, nitrogen, and hydrocarbons using SAFT".journal of chemical thermodynamics 39.3(2007):417-425.
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