Synthesis of glycidyl methacrylate modified hyper-cross-linked resins and enhancing their adsorptions toward levulinic acid and furfural from sugarcane bagasse hydrolysate

doi:10.1002/jctb.6440

	Synthesis of glycidyl methacrylate modified hyper-cross-linked resins and enhancing their adsorptions toward levulinic acid and furfural from sugarcane bagasse hydrolysate
	Zhang, Liquan 1,2,3,4; Wang, Can 1,2,3; Zhang, Hairong 1,2,3; Guo, Haijun 1,2,3; Xiong, Lian 1,2,3; Li, Hailong 1,2,3; Chen, Xuefang 1,2,3; Chen, Xinde 1,2,3
刊名	JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY
	2020-05-30
页码	12
关键词	hyper-cross-linked resin adsorption properties sugarcane bagasse hydrolysate levulinic acid furfural
ISSN号	0268-2575
DOI	10.1002/jctb.6440
通讯作者	Chen, Xuefang(chenxf@ms.giec.ac.cn) ; Chen, Xinde(cxd_cxd@hotmail.com)
英文摘要	Levulinic acid (LA) and furfural are important biomass-based platform compounds. During the preparation of LA and furfural from lignocellulosic biomass, other organic chemicals including sugars, formic acid, acetic acid, and acid-soluble lignin (ASL) will be produced simultaneously. Thus, the purification of LA and furfural is an important process. In this work, a series of glycidyl methacrylate (GMA) modified hyper-cross-linked resins were synthesized and the mechanism of pore formation of the resins was studied. Furthermore, the effect of their textural properties on adsorption performance towards LA and furfural was investigated. RESULTS The hyper-cross-linked resin modified with 50 wt% GMA (PC-4) achieved the best adsorption performance. The adsorption capacities of LA and furfural onto PC-4 were 100.81 and 40.22 mg g(-1), respectively, which were 2423.76% and 249.24% higher than the un-modified resin HQ-8, and 31.0% and 22.7% higher than its precursor PR-4. During desorption process, the average desorption ratio of LA and furfural were 94.96% and 97.86%, respectively. Moreover, PC-4 also showed a good adsorption performance towards formic acid, acetic acid, and ASL, while sugar loss rate was about 5%. This study not only reported a potential adsorbent, PC-4, for the comprehensive utilization of sugarcane bagasse hydrolysate, but it also studied the relationship between synthesis conditions, resin structures, and its adsorption performance of GMA modified hyper-cross-linked resins, which provides a guidance for new adsorbent design.
资助项目	Project of National Natural Science Foundation of China[51876207] ; Science and Technology Planning Project of Guangdong Province, China[2017A010103043] ; foundation of Key Laboratory of Renewable Energy, Chinese Academy of Sciences[E0290107] ; foundation of Guangdong Basic and Applied Basic Research Foundation[2019A1515011843] ; foundation of Pearl River S&T Nova Program of Guangzhou[201806010107] ; foundation of Pearl River S&T Nova Program of Guangzhou[201710010096]
WOS关键词	FERMENTATION INHIBITORS ; AQUEOUS-SOLUTION ; RICE STRAW ; LIGNOCELLULOSIC BIOMASS ; CONTROLLABLE SYNTHESIS ; SALICYLIC-ACID ; SULFURIC-ACID ; LIGNIN ; SIMULATION ; REMOVAL
WOS研究方向	Biotechnology & Applied Microbiology ; Chemistry ; Engineering
语种	英语
出版者	WILEY
WOS记录号	WOS:000536386800001
资助机构	Project of National Natural Science Foundation of China ; Science and Technology Planning Project of Guangdong Province, China ; foundation of Key Laboratory of Renewable Energy, Chinese Academy of Sciences ; foundation of Guangdong Basic and Applied Basic Research Foundation ; foundation of Pearl River S&T Nova Program of Guangzhou
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/27174]
专题	中国科学院广州能源研究所
通讯作者	Chen, Xuefang; Chen, Xinde
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, 2 Nengyuan Rd, Guangzhou 510640, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou, Peoples R China 4.Univ Chinese Acad Sci, Beijing, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Liquan,Wang, Can,Zhang, Hairong,et al. Synthesis of glycidyl methacrylate modified hyper-cross-linked resins and enhancing their adsorptions toward levulinic acid and furfural from sugarcane bagasse hydrolysate[J]. JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY,2020:12.
APA	Zhang, Liquan.,Wang, Can.,Zhang, Hairong.,Guo, Haijun.,Xiong, Lian.,...&Chen, Xinde.(2020).Synthesis of glycidyl methacrylate modified hyper-cross-linked resins and enhancing their adsorptions toward levulinic acid and furfural from sugarcane bagasse hydrolysate.JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY,12.
MLA	Zhang, Liquan,et al."Synthesis of glycidyl methacrylate modified hyper-cross-linked resins and enhancing their adsorptions toward levulinic acid and furfural from sugarcane bagasse hydrolysate".JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY (2020):12.