Enhancement of Light Olefins Selectivity Over N-Doped Fischer-Tropsch Synthesis Catalyst Supported on Activated Carbon Pretreated with KMnO4

doi:10.3390/catal9060505

	Enhancement of Light Olefins Selectivity Over N-Doped Fischer-Tropsch Synthesis Catalyst Supported on Activated Carbon Pretreated with KMnO4
	Tian, Zhipeng 1,2; Wang, Chenguang 1; Si, Zhan 1; Wen, Chengyan 1; Xu, Ying 1; Lv, Wei 1; Chen, Lungang 1; Zhang, Xinghua 1; Ma, Longlong 1
刊名	CATALYSTS
	2019-06-01
卷号	9 期号:6 页码:10
关键词	nitrogen-doping iron nitrides light olefins CO hydrogenation KMnO4 pretreatment
ISSN号	2073-4344
DOI	10.3390/catal9060505
通讯作者	Wang, Chenguang(wangcg@ms.giec.ac.cn)
英文摘要	Ammonium iron citrate was used as an iron precursor in order to prepare N-doped catalysts supported on KMnO4 pretreated activated carbon (10MnK-AC). Iron nitride was synthesized in company with the formation of alpha-Fe2O3 on 10MnK-AC. The characterizations of the catalysts show that nitrogen atoms were doped into iron lattice rather than the networks of the carbon support. The performance of Fischer-Tropsch synthesis to light olefins (FTO) suggest an improvement in O/P ratio (olefins to paraffins molar ratio of C-2-C-4) over the iron catalysts supported on 10MnK-AC. The further promotion of light olefins selectivity (up to 44.7%) was obtained over FeN-10MnK-AC catalyst owing to the collaborative contribution of the electron donor effect of nitrogen and the suppression effect on the second hydrogenation over 10MnK-AC support.
资助项目	NSFC (National Natural Science Foundation of China Project)[51476175] ; NSFC (National Natural Science Foundation of China Project)[51776206] ; CAS Pioneer Hundred Talents Program
WOS关键词	IRON CATALYSTS ; CO HYDROGENATION ; NITROGEN ; NANOTUBES ; SYNGAS ; OLIGOMERIZATION ; NANOPARTICLES ; CONVERSION ; POTASSIUM ; MOSSBAUER
WOS研究方向	Chemistry
语种	英语
出版者	MDPI
WOS记录号	WOS:000473808000018
资助机构	NSFC (National Natural Science Foundation of China Project) ; CAS Pioneer Hundred Talents Program
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/25402]
专题	中国科学院广州能源研究所
通讯作者	Wang, Chenguang
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangdong Prov Key Lab New & Renewable Energy Res, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Tian, Zhipeng,Wang, Chenguang,Si, Zhan,et al. Enhancement of Light Olefins Selectivity Over N-Doped Fischer-Tropsch Synthesis Catalyst Supported on Activated Carbon Pretreated with KMnO4[J]. CATALYSTS,2019,9(6):10.
APA	Tian, Zhipeng.,Wang, Chenguang.,Si, Zhan.,Wen, Chengyan.,Xu, Ying.,...&Ma, Longlong.(2019).Enhancement of Light Olefins Selectivity Over N-Doped Fischer-Tropsch Synthesis Catalyst Supported on Activated Carbon Pretreated with KMnO4.CATALYSTS,9(6),10.
MLA	Tian, Zhipeng,et al."Enhancement of Light Olefins Selectivity Over N-Doped Fischer-Tropsch Synthesis Catalyst Supported on Activated Carbon Pretreated with KMnO4".CATALYSTS 9.6(2019):10.