新型铁铜铝三元复合氧化物除磷性能与机制研究

doi:DOI: 10.13671/j.hjkxxb.2017.0282

CORC > 烟台海岸带研究所 > 中国科学院烟台海岸带研究所 > 海岸带生物学与生物资源利用重点实验室 > 海岸带生物学与生物资源利用所重点实验室

	新型铁铜铝三元复合氧化物除磷性能与机制研究
	杨雪 ; 陈静 ; 李秋梅 ; 张高生 ; 刘子全
刊名	环境科学学报
	2017-07-24
卷号	38 期号:2 页码:501-510
关键词	Fe-Cu-Al trimetal oxide phosphate adsorption mechanism adsorbent 铁铜铝三元复合氧化物磷吸附机制吸附剂
ISSN号	0253-2468
DOI	DOI: 10.13671/j.hjkxxb.2017.0282
其他题名	The adsorption of phosphate on a novel Fe-Cu-Al trimetal oxide: Behavior and mechanism
产权排序	(1) 烟台大学环境与材料工程学院 ; (2) 中国科学院烟台海岸带研究所中国科学院海岸带环境过程与生态修复重点实验室山东省海岸带环境工程技术研究中心 ; (3) 烟台大学海洋学院
文献子类	Article
英文摘要	A novel Fe-Cu-Al trimetal oxide adsorbent was fabricated via a facile co-precipitation process,assessed for effective phosphate adsorption,and was characterized by multiple techniques. The isotherm data was well fitted by the Freundlich model and the maximal adsorption capacity was 62.6 mg·g~(-1) at pH 7.0,which outperformed the majority of phosphate adsorbents reported. The adsorption of phosphate was very fast and the Elovich model was more suitable for describing the kinetic data. The adsorption of P was pH-depended and the efficiency decreased with increasing pH; whereas ionic strength had little influence on the adsorption. Further,coexisting anion inhibited phosphate adsorption and the effects decreased in the order of SiO_3~(2 -) >SO_2 - 4 >CO_3~(2 -) > Cl~-. In contrast,coexisting cations Ca~(2+) and Mg~(2+) slightly enhanced phosphate adsorption. Results of Zeta potential,FTIR and XPS analysis indicate specific adsorption occurred at the aqueous phosphate /adsorbent interface. Phosphate was probably removed by replacing the hydroxyl groups on the surface of the adsorbent and forming inner-sphere complex. Leaching of Fe~(3+),Cu~(2+) and Al~(3+) was low at the pH range of 5.0~ 8.5. This further makes Fe- Cu-Al trimetal oxide a promising adsorbent for phosphate removal from water.
WOS关键词	Environmental Sciences & Ecology
WOS研究方向	Environmental Sciences & Ecology ; 环境科学与生态学
语种	中文
CSCD记录号	CSCD:6160776
内容类型	期刊论文
源URL	[http://ir.yic.ac.cn/handle/133337/24300]
专题	烟台海岸带研究所_海岸带生物学与生物资源利用所重点实验室烟台海岸带研究所_污染过程与控制实验室
作者单位	1.烟台大学环境与材料工程学院; 2.中国科学院烟台海岸带研究所中国科学院海岸带环境过程与生态修复重点实验室山东省海岸带环境工程技术研究中心; 3.烟台大学海洋学院
推荐引用方式 GB/T 7714	杨雪,陈静,李秋梅,等. 新型铁铜铝三元复合氧化物除磷性能与机制研究[J]. 环境科学学报,2017,38(2):501-510.
APA	杨雪,陈静,李秋梅,张高生,&刘子全.(2017).新型铁铜铝三元复合氧化物除磷性能与机制研究.环境科学学报,38(2),501-510.
MLA	杨雪,et al."新型铁铜铝三元复合氧化物除磷性能与机制研究".环境科学学报 38.2(2017):501-510.