Breaking the permeability-selectivity trade-off in thin-film composite polyamide membranes with a PEG-b-PSF-b-PEG block copolymer ultrafiltration membrane support through post-annealing treatment

doi:10.1038/s41427-019-0114-1

CORC > 烟台海岸带研究所 > 中国科学院烟台海岸带研究所 > 山东省海岸带环境工程技术研究中心

	Breaking the permeability-selectivity trade-off in thin-film composite polyamide membranes with a PEG-b-PSF-b-PEG block copolymer ultrafiltration membrane support through post-annealing treatment
	An, XC ; Hu, YX ; Wang, N ; Wang, T ; Liu, ZY
刊名	NPG ASIA MATERIALS
	2019-03-21
卷号	11 页码:13
关键词	INTERNAL CONCENTRATION POLARIZATION OSMOSIS MEMBRANES PERFORMANCE NANOFIBERS LAYER WATER DESALINATION IMPROVEMENT TECHNOLOGY ENERGY
ISSN号	1884-4049
DOI	10.1038/s41427-019-0114-1
产权排序	[An, Xiaochan ; Hu, Yunxia] Tianjin Polytech Univ, Sch Mat Sci & Engn, Natl Ctr Int Res Membrane Sci & Technol, State Key Lab Separat Membranes & Membrane Proc, Tianjin 300387, Peoples R China ; [An, Xiaochan ; Wang, Ning ; Wang, Tao ; Liu, Zhongyun] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Res Ctr Coastal Environm Engn & Technol Shandong, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China ; [An, Xiaochan] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
文献子类	Article
英文摘要	In this work, amphiphilic polyethylene glycol-block-polysulfone-block-polyethylene glycol (PEG-b-PSF-b-PEG) was used as a membrane support to fabricate a high-performance thin-film composite (TFC) forward osmosis (FO) membrane. A facile post-annealing approach was developed to simultaneously improve the water permeability and antifouling property of the TFC membrane having the PEG-b-PSF-b-PEG support without sacrificing its selectivity. The experimental results illustrate that a highly crosslinked polyamide with low reverse salt flux could be formed on the PEG-b-PSF-b-PEG support, and the post-annealing treatment could tailor the membrane structure and properties of the PEG-b-PSF-b-PEG support to decrease its structure parameter without affecting the polyamide. The annealed TFC membrane exhibited excellent permeability-selectivity, with a high A/B ratio of 19.6 bar(-1) (water permeability coefficient A of 1.76 LMH.bar(-1) and NaCl permeability coefficient B of 0.09 LMH). The static and dynamic antifouling performances of the annealed TFC membrane were also demonstrated, finding that little bovine serum albumin (BSA) was adsorbed on the PEG-b-PSF-b-PEG support surface, and a reduced water flux decline and a high water recovery were achieved compared with those of the control sample. Our work demonstrates that the amphiphilic PEG-b-PSF-b-PEG membrane can work as an ideal TFC support to break the permeability-selectivity trade-off of the TFC FO membrane and to improve its antifouling properties through post-annealing treatment.
WOS关键词	INTERNAL CONCENTRATION POLARIZATION ; OSMOSIS MEMBRANES ; PERFORMANCE ; NANOFIBERS ; LAYER ; WATER ; DESALINATION ; IMPROVEMENT ; TECHNOLOGY ; ENERGY
WOS研究方向	Materials Science, Multidisciplinary
语种	英语
WOS记录号	WOS:000462373900001
资助机构	National Natural Science Foundation of ChinaNational Natural Science Foundation of China [21476249, 51708408] ; Program for Innovative Research Team in University of Tianjin [TD13-5044] ; Chang-jiang Scholars and Innovative Research Team in the University of Ministry of Education, China [IRT-17R80] ; Science and Technology Plans of Tianjin [17PTSYJC00060]
内容类型	期刊论文
源URL	[http://ir.yic.ac.cn/handle/133337/24973]
专题	烟台海岸带研究所_山东省海岸带环境工程技术研究中心烟台海岸带研究所_海岸带生物学与生物资源利用所重点实验室
作者单位	1.Tianjin Polytech Univ, Sch Mat Sci & Engn, Natl Ctr Int Res Membrane Sci & Technol, State Key Lab Separat Membranes & Membrane Proc, Tianjin 300387, Peoples R China; 2.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Res Ctr Coastal Environm Engn & Technol Shandong, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China; 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	An, XC,Hu, YX,Wang, N,et al. Breaking the permeability-selectivity trade-off in thin-film composite polyamide membranes with a PEG-b-PSF-b-PEG block copolymer ultrafiltration membrane support through post-annealing treatment[J]. NPG ASIA MATERIALS,2019,11:13.
APA	An, XC,Hu, YX,Wang, N,Wang, T,&Liu, ZY.(2019).Breaking the permeability-selectivity trade-off in thin-film composite polyamide membranes with a PEG-b-PSF-b-PEG block copolymer ultrafiltration membrane support through post-annealing treatment.NPG ASIA MATERIALS,11,13.
MLA	An, XC,et al."Breaking the permeability-selectivity trade-off in thin-film composite polyamide membranes with a PEG-b-PSF-b-PEG block copolymer ultrafiltration membrane support through post-annealing treatment".NPG ASIA MATERIALS 11(2019):13.