Distribution and dry deposition of alternative and legacy perfluoroalkyl and polyfluoroalkyl substances in the air above the Bohai and Yellow Seas, China

doi:10.1016/j.atmosenv.2018.08.052

CORC > 烟台海岸带研究所 > 中国科学院烟台海岸带研究所 > 中科院海岸带环境过程与生态修复重点实验室 > 近岸生态与环境实验室

	Distribution and dry deposition of alternative and legacy perfluoroalkyl and polyfluoroalkyl substances in the air above the Bohai and Yellow Seas, China
	Fang, Xiangguang ; Wang, Qi ; Zhao, Zhen ; Tang, Jianhui ; Tian, Chongguo ; Yao, Yiming ; Yu, Junchao ; Sun, Hongwen
刊名	ATMOSPHERIC ENVIRONMENT
	2018-11
卷号	192 页码:128-135
关键词	PFAS Gas/particle distribution Dry deposition Marine air
ISSN号	1352-2310
DOI	10.1016/j.atmosenv.2018.08.052
产权排序	[Fang, Xiangguang ; Wang, Qi ; Zhao, Zhen ; Yao, Yiming ; Yu, Junchao ; Sun, Hongwen] Nankai Univ, Key Lab Pollut Proc & Environm Criteria, Coll Environm Sci & Engn, MOE, Tianjin 300350, Peoples R China ; [Zhao, Zhen] Chinese Acad Sci, State Key Lab Organ Geochem, Guangzhou Inst Geochem, Guangzhou 510640, Guangdong, Peoples R China ; [Tang, Jianhui ; Tian, Chongguo] Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China
文献子类	Article
英文摘要	A total of 26 alternative and legacy perfluoroalkyl and polyfluoroalkyl substances (PFASs) were investigated in air collected above the Bohai and Yellow Seas during a research cruise between June 28 and July 15, 2016. Sigma PFAS concentrations ranged from 70 pg m(-3) to 430 pg m(-3) (mean 230 +/- 100 pg m(-3)). Trifluoroacetic acid (TFA, mean 120 +/- 80 pg m(-3)) and 8:2 fluorotelomer alcohol (8:2 FTOH, mean 34 +/- 46 pg m(-3)) were the predominating compounds of ionizable PFASs (i-PFASs) and neutral PFASs (n-PFASs), respectively. The contributions of C-4 and C-6 i-PFASs were higher than those of C-8 i-PFASs. Alternative substances, such as chlorinated 6:2 polyfluoroalkyl ether sulfonic acids (Cl-6:2 PFESA, mean 1.6 +/- 1.2 pg m(-3)) and diPAPs (mean 1.6 +/- 1.3 pg m(-3)), were only detected on the filter. The distribution coefficient of 10:2 FTOH was higher than 8:2 FTOH, which could be explained by the length of the carbon chain. The gas phase dry deposition velocities were simulated, and the values ranged from 0.08 +/- 0.12 cm s(-1) to 0.85 +/- 0.28 cm s(-1). For i-PFASs and diPAPs, the estimated fluxes of the particle phase were higher than those of the gas phase. For n-PFASs and TFA, the gas phase deposition played a key role. The Sigma PFASs dry deposition fluxes were 11-290 ng (m(2) d)(-1) (mean 72 +/- 67 ng (m(2) d)(-1)). The measurement of the concentrations in the gas and particle phases simultaneously provided a more comprehensive understanding of PFAS behaviours in air.
WOS关键词	PERFLUORINATED CARBOXYLIC-ACIDS ; GAS/PARTICLE PARTITION-COEFFICIENTS ; POLYFLUORINATED ALKYL SUBSTANCES ; POLY-/PERFLUOROALKYL SUBSTANCES ; POLYBROMINATED DIPHENYL ETHERS ; NORTHERN GERMAN COAST ; WATER TREATMENT-PLANT ; FLUOROALKYL SUBSTANCES ; FLUOROTELOMER ALCOHOLS ; ATMOSPHERIC CHEMISTRY
WOS研究方向	Environmental Sciences ; Meteorology & Atmospheric Sciences
语种	英语
WOS记录号	WOS:000447819900012
资助机构	National Natural Science Foundation of China [41603101, 41773138, 41573097] ; State Key Laboratory of Organic Geochemistry, GIGCAS [SKLOG-201609]
内容类型	期刊论文
源URL	[http://ir.yic.ac.cn/handle/133337/24562]
专题	烟台海岸带研究所_近岸生态与环境实验室烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室
作者单位	1.Chinese Acad Sci, State Key Lab Organ Geochem, Guangzhou Inst Geochem, Guangzhou 510640, Guangdong, Peoples R China; 2.Nankai Univ, Key Lab Pollut Proc & Environm Criteria, Coll Environm Sci & Engn, MOE, Tianjin 300350, Peoples R China; 3.Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China
推荐引用方式 GB/T 7714	Fang, Xiangguang,Wang, Qi,Zhao, Zhen,et al. Distribution and dry deposition of alternative and legacy perfluoroalkyl and polyfluoroalkyl substances in the air above the Bohai and Yellow Seas, China[J]. ATMOSPHERIC ENVIRONMENT,2018,192:128-135.
APA	Fang, Xiangguang.,Wang, Qi.,Zhao, Zhen.,Tang, Jianhui.,Tian, Chongguo.,...&Sun, Hongwen.(2018).Distribution and dry deposition of alternative and legacy perfluoroalkyl and polyfluoroalkyl substances in the air above the Bohai and Yellow Seas, China.ATMOSPHERIC ENVIRONMENT,192,128-135.
MLA	Fang, Xiangguang,et al."Distribution and dry deposition of alternative and legacy perfluoroalkyl and polyfluoroalkyl substances in the air above the Bohai and Yellow Seas, China".ATMOSPHERIC ENVIRONMENT 192(2018):128-135.