Ag-Nanoparticles@Bacterial-Nanocellulose as 3D Flexible and Robust Surface-Enhanced Raman Scattering Substrate | |
Huo Dexian; Chen Bin; Meng Guowen; Huang Zhulin; Li Mingtao; Lei Yong | |
刊名 | ACS Applied Materials & Interfaces |
2020-10 | |
关键词 | surface-enhanced Raman scattering bacterial nanocellulose Ag-nanoparticles flexible hybrid substrate rapid detection |
ISSN号 | 1944-8244 |
DOI | 10.1021/acsami.0c13828 |
英文摘要 | We present a well-designed, low-cost, and simple synthetic approach to realizing the hybrid composites of Ag nanoparticle-decorated bacterial nanocellulose (denoted as Ag-NPs@BNC) as a three-dimensional (3D) flexible surface-enhanced Raman scattering (SERS) substrate with ultrahigh SERS sensitivity, excellent signal reproducibility, and stability. The homogeneous Ag-NPs with high density were in situ grown on the networked BNC fibers by the controlled silver mirror reaction and volume shrinkage treatment, which created uniformly distributed SERS "hot spots" in the 3D networked hybrid substrate. Attributed to these unique 3D hot spots, the as-presented Ag-NPs@BNC substrates exhibited ultrahigh sensitivity and good spectral reproducibility. Moreover, the hydrophilic BNC exhibits good permeability and adsorption performances, which could capture the target molecules in the highly active hot spot areas to further improve the SERS sensitivity. As a result, not only dye molecules (rhodamine 6G) but also toxic organic pollutants such as 2-naphthalenethiol and thiram have been detected using the hybrid substrates as SERS substrates, with sensitivities of 1.6 * 10-8 and 3.8 * 10-9 M, respectively. The good linear response of the intensity and the logarithmic concentration revealed promising applications in the rapid and quantitative detection of toxic organic pollutants. Besides, this self-supported Ag-NPs@BNC substrate demonstrated good stability and flexibility for varied detection conditions. Therefore, the 3D networked, flexible, ultrasensitive, and stable Ag-NPs@BNC substrate shows potential as a versatile SERS substrate in the rapid identification of various organic molecules. |
URL标识 | 查看原文 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/92855] |
专题 | 合肥物质科学研究院_中科院固体物理研究所 |
通讯作者 | Chen Bin; Meng Guowen; Lei Yong |
作者单位 | 1.University of Science and Technology of China, Hefei 230026, China. 2.Key Laboratory of Materials Physics and Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences, P.O. Box 1129, Hefei 230031, China. 3.Institut fur Physik & IMN MacroNano@ (ZIK), Technische Universitat Imenau, 98693 Ilmenau, Germany. |
推荐引用方式 GB/T 7714 | Huo Dexian,Chen Bin,Meng Guowen,et al. Ag-Nanoparticles@Bacterial-Nanocellulose as 3D Flexible and Robust Surface-Enhanced Raman Scattering Substrate[J]. ACS Applied Materials & Interfaces,2020. |
APA | Huo Dexian,Chen Bin,Meng Guowen,Huang Zhulin,Li Mingtao,&Lei Yong.(2020).Ag-Nanoparticles@Bacterial-Nanocellulose as 3D Flexible and Robust Surface-Enhanced Raman Scattering Substrate.ACS Applied Materials & Interfaces. |
MLA | Huo Dexian,et al."Ag-Nanoparticles@Bacterial-Nanocellulose as 3D Flexible and Robust Surface-Enhanced Raman Scattering Substrate".ACS Applied Materials & Interfaces (2020). |
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