Gold Nanoparticle-Based Peroxyoxalate Chemiluminescence System for Highly Sensitive and Rapid Detection of Thiram Pesticides

doi:10.1021/acsanm.1c00305

	Gold Nanoparticle-Based Peroxyoxalate Chemiluminescence System for Highly Sensitive and Rapid Detection of Thiram Pesticides
	Li, Lingfei 2,3; Lin, Dan 1,3; Yang, Fan 1,3; Xiao, Youyu 4; Yang, Liang 1,3; Yu, Shaoming 2; Jiang, Changlong 1,3
刊名	ACS APPLIED NANO MATERIALS
	2021-04-23
卷号	4
关键词	chemiluminescence nanosensor gold nanoparticles sensitive detection thiram rapid
ISSN号	2574-0970
DOI	10.1021/acsanm.1c00305
通讯作者	Yang, Liang(yangliang@iim.ac.cn) ; Yu, Shaoming(shmyu@hfut.edu.cn) ; Jiang, Changlong(cljiang@iim.ac.cn)
英文摘要	Abuse and inappropriate disposal of the pesticide thiram can be hazardous to human health and sustainable development of the environment. Herein, we designed a peroxyoxalate chemiluminescence-based nanosensing system composed of bis(2,4,6-trichlorophenyl)oxalate (TCPO), hydrogen peroxide (H2O2), and specific-sized gold nanoparticles (Au NPs) for highly sensitive, rapid, and selective detection of thiram pesticide via a chemiluminescence "on-off" phenomenon. The nanoscale sensing system produced strong chemiluminescence through excited specific-sized Au NPs by the energy transfer from peroxyoxalate chemically; however, the chemiluminescence was very sensitive to thiram and decreased gradually because the discrete energy level of Au NPs changed after interacting with thiram to form an aggregated complex through intense Au-S bonds. The proposed chemiluminescence-based nanosensor could achieve the determination of thiram with a sensitive and low limit of detection (LOD) of 0.35 nM, within a detection time of 40 s. The nanoscale sensing system reported herein was simple, rapid, low cost, and highly sensitive and selective for sulfhydryl-containing environmentally hazardous substances like thiram pesticide residues in fruits, vegetables, milk, and environmental water, promoting the development and application of nanomaterial-based chemiluminescence sensing in the fields of food and environment safety monitoring.
资助项目	National Natural Science Foundation of China[21671052] ; National Natural Science Foundation of China[21806168] ; Key Research and Development Program of Anhui Province[202004d07020013] ; Key Research and Development Program of Anhui Province[1804a07020103]
WOS关键词	FUNGICIDE THIRAM ; EXTRACTION ; MONOLAYERS ; RESIDUES ; THIOLS ; PLANTS ; STATE ; WATER ; SIZE
WOS研究方向	Science & Technology - Other Topics ; Materials Science
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000644473900069
资助机构	National Natural Science Foundation of China ; Key Research and Development Program of Anhui Province
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/122104]
专题	中国科学院合肥物质科学研究院
通讯作者	Yang, Liang; Yu, Shaoming; Jiang, Changlong
作者单位	1.Chinese Acad Sci, State Key Lab Transducer Technol, Hefei 230031, Anhui, Peoples R China 2.Hefei Univ Technol, Sch Chem & Chem Engn, Hefei 230009, Anhui, Peoples R China 3.Chinese Acad Sci, Inst Solid State Phys, Hefei Inst Phys Sci, Hefei 230031, Anhui, Peoples R China 4.Nanjing Inst Prod Qual Inspect, Nanjing 210028, Jiangsu, Peoples R China
推荐引用方式 GB/T 7714	Li, Lingfei,Lin, Dan,Yang, Fan,et al. Gold Nanoparticle-Based Peroxyoxalate Chemiluminescence System for Highly Sensitive and Rapid Detection of Thiram Pesticides[J]. ACS APPLIED NANO MATERIALS,2021,4.
APA	Li, Lingfei.,Lin, Dan.,Yang, Fan.,Xiao, Youyu.,Yang, Liang.,...&Jiang, Changlong.(2021).Gold Nanoparticle-Based Peroxyoxalate Chemiluminescence System for Highly Sensitive and Rapid Detection of Thiram Pesticides.ACS APPLIED NANO MATERIALS,4.
MLA	Li, Lingfei,et al."Gold Nanoparticle-Based Peroxyoxalate Chemiluminescence System for Highly Sensitive and Rapid Detection of Thiram Pesticides".ACS APPLIED NANO MATERIALS 4(2021).