G-type antiferromagnetism of Mn ions in A-site-ordered perovskite LaMn3Rh4O12 and La0.8Ca0.2Mn3Rh4O12

doi:10.1016/j.physleta.2021.127258

	G-type antiferromagnetism of Mn ions in A-site-ordered perovskite LaMn3Rh4O12 and La0.8Ca0.2Mn3Rh4O12
	Ni, Meiyan 1; Zhang, Shoubao 1; Han, Shuo 1; Liu, Xiaoli 1; Lu, Hongyan 1; Zhou, Shaoshuai 1; Zhao, Hongyan 1; Zhu, Xuebin 2
刊名	PHYSICS LETTERS A
	2021-05-06
卷号	397
关键词	High pressure synthesis Antiferromagnetic transition First principles calculation Semiconductor
ISSN号	0375-9601
DOI	10.1016/j.physleta.2021.127258
通讯作者	Zhang, Shoubao(zhang.shoubao@qfnu.edu.cn) ; Zhu, Xuebin(xbzhu@issp.ac.cn)
英文摘要	A-site-ordered perovskites LaMn3Rh4O12 and La0.8Ca0.2Mn3Rh4O12 were prepared by using high-pressure and high temperature method. Structural and BVS analyses suggest that the valence states of Mn and Rh ions are both +3 in LaMn3Rh4O12. Partial Ca-doping introduced some Mn4+ ions, which are transferred to B site and leave some deficiencies at A' site. Localized electrons of Mn and Rh ions induce a semiconducting behavior. Combined with the results of the first principles calculation, it is believed that the interaction between high spin Mn3+ ions induce a G-type antiferromagnetism, while low spin Rh3+ ions have no magnetic contribution. And also, there is no interaction between Mn and Rh ions. The results confirm that non-Jahn-Teller distorted Mn4+ ion cannot occupy A' site in the A-site-ordered perovskite, even partly. (C) 2021 Elsevier B.V. All rights reserved.
资助项目	National Natural Science Foundation of China (NSFC)[11904197] ; National Natural Science Foundation of China (NSFC)[11804188] ; Natural Science Foundation of Shandong Province, China[ZR2019QF010] ; Natural Science Foundation of Shandong Province, China[ZR2018PA010] ; Project of Introduction and Cultivation for Young Innovative Talents in Colleges and Universities of Shandong Province
WOS研究方向	Physics
语种	英语
出版者	ELSEVIER
WOS记录号	WOS:000632994800005
资助机构	National Natural Science Foundation of China (NSFC) ; Natural Science Foundation of Shandong Province, China ; Project of Introduction and Cultivation for Young Innovative Talents in Colleges and Universities of Shandong Province
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/121449]
专题	中国科学院合肥物质科学研究院
通讯作者	Zhang, Shoubao; Zhu, Xuebin
作者单位	1.Qufu Normal Univ, Sch Phys & Phys Engn, Qufu 273165, Shandong, Peoples R China 2.Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Peoples R China
推荐引用方式 GB/T 7714	Ni, Meiyan,Zhang, Shoubao,Han, Shuo,et al. G-type antiferromagnetism of Mn ions in A-site-ordered perovskite LaMn3Rh4O12 and La0.8Ca0.2Mn3Rh4O12[J]. PHYSICS LETTERS A,2021,397.
APA	Ni, Meiyan.,Zhang, Shoubao.,Han, Shuo.,Liu, Xiaoli.,Lu, Hongyan.,...&Zhu, Xuebin.(2021).G-type antiferromagnetism of Mn ions in A-site-ordered perovskite LaMn3Rh4O12 and La0.8Ca0.2Mn3Rh4O12.PHYSICS LETTERS A,397.
MLA	Ni, Meiyan,et al."G-type antiferromagnetism of Mn ions in A-site-ordered perovskite LaMn3Rh4O12 and La0.8Ca0.2Mn3Rh4O12".PHYSICS LETTERS A 397(2021).