Fe-Co Alloyed Nanoparticles Catalyzing Efficient Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol in Water

doi:10.1002/anie.202009913

	Fe-Co Alloyed Nanoparticles Catalyzing Efficient Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol in Water
	Lv, Yang 2; Han, Miaomiao 2; Gong, Wanbing 2; Wang, Dongdong 2; Chen, Chun 2; Wang, Guozhong 2; Zhang, Haimin 2; Zhao, Huijun 1,2
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2020-10-23
关键词	cinnamaldehyde Fe-Co nanoalloys H2O solvent metal– organic frameworks selective hydrogenation
ISSN号	1433-7851
DOI	10.1002/anie.202009913
通讯作者	Gong, Wanbing(wbgong@issp.ac.cn) ; Zhao, Huijun(h.zhao@griffith.edu.au)
英文摘要	Selective hydrogenation of C=O against the conjugated C=C in cinnamaldehyde (CAL) is indispensable to produce cinnamyl alcohol (COL). Nonetheless, it is challenged by the low selectivity and the need to use organic solvents. Herein, for the first time, we report the use of Fe-Co alloy nanoparticles (NPs) on N-doped carbon support as a selective hydrogenation catalyst to efficiently convert CAL to COL. The resultant catalyst with the optimized Fe/Co ratio of 0.5 can achieve an exceptional COL selectivity of 91.7 % at a CAL conversion of 95.1 % in pure water medium under mild reaction conditions, ranking it the best performed catalyst reported to date. The experimental results confirm that the COL selectivity and CAL conversion efficiency are, respectively promoted by the presence of Fe and Co, while the synergism of the alloyed Fe-Co is the key to concurrently achieve high COL selectivity and CAL conversion efficiency.
资助项目	Natural Science Foundation of China[51871209] ; Natural Science Foundation of China[51902311] ; Postdoctoral Science Foundation of China[2019M652223]
WOS关键词	METAL-ORGANIC FRAMEWORKS ; SELECTIVE HYDROGENATION ; CATALYSTS
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000582370700001
资助机构	Natural Science Foundation of China ; Postdoctoral Science Foundation of China
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/104621]
专题	中国科学院合肥物质科学研究院
通讯作者	Gong, Wanbing; Zhao, Huijun
作者单位	1.Griffith Univ, Ctr Clean Environm & Energy, Gold Coast Campus, Southport, Qld 4222, Australia 2.Chinese Acad Sci, Anhui Key Lab Nanomat & Nanotechnol, CAS Ctr Excellence Nanosci,Inst Solid State Phys, Key Lab Mat Phys,Ctr Environm & Energy Nanomat, Hefei 230031, Peoples R China
推荐引用方式 GB/T 7714	Lv, Yang,Han, Miaomiao,Gong, Wanbing,et al. Fe-Co Alloyed Nanoparticles Catalyzing Efficient Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol in Water[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2020.
APA	Lv, Yang.,Han, Miaomiao.,Gong, Wanbing.,Wang, Dongdong.,Chen, Chun.,...&Zhao, Huijun.(2020).Fe-Co Alloyed Nanoparticles Catalyzing Efficient Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol in Water.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
MLA	Lv, Yang,et al."Fe-Co Alloyed Nanoparticles Catalyzing Efficient Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol in Water".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020).