One-Pot Methylenation-Cyclization Employing Two Molecules of CO2 with Arylamines and Enaminones

	One-Pot Methylenation-Cyclization Employing Two Molecules of CO2 with Arylamines and Enaminones
	Zhao, Yulei; Liu, Xu; Zheng, Lijun; Du, Yulan; Shi, Xinrui; Liu, Yunlin; Yan, Zhengquan; You, Jinmao; Jiang, Yuanye
刊名	JOURNAL OF ORGANIC CHEMISTRY
	2020
卷号	85 期号:2
英文摘要	One-pot methylenation-cyclization employing two molecules of CO2 with enaminones and primary aromatic amines was discussed for the first time to access cyclized products. This 1,5,7-triazabicyclo[4.4.0]dec-5-ene and ZnCl2-catalyzed procedure was characterized by the selective conversion of two molecules of CO2 into methylene groups in a multicomponent cyclization reaction. According to the computational study and control experiments, the reaction might proceed through the generation of bis(silyl)acetal and condensation of arylamine and aza-Diels-Alder processes. Moreover, the resulting products will probably be potential organic building blocks with adjustable photophysical properties.
内容类型	期刊论文
源URL	[http://210.75.249.4/handle/363003/60437]
专题	西北高原生物研究所_中国科学院西北高原生物研究所
推荐引用方式 GB/T 7714	Zhao, Yulei,Liu, Xu,Zheng, Lijun,et al. One-Pot Methylenation-Cyclization Employing Two Molecules of CO2 with Arylamines and Enaminones[J]. JOURNAL OF ORGANIC CHEMISTRY,2020,85(2).
APA	Zhao, Yulei.,Liu, Xu.,Zheng, Lijun.,Du, Yulan.,Shi, Xinrui.,...&Jiang, Yuanye.(2020).One-Pot Methylenation-Cyclization Employing Two Molecules of CO2 with Arylamines and Enaminones.JOURNAL OF ORGANIC CHEMISTRY,85(2).
MLA	Zhao, Yulei,et al."One-Pot Methylenation-Cyclization Employing Two Molecules of CO2 with Arylamines and Enaminones".JOURNAL OF ORGANIC CHEMISTRY 85.2(2020).