Hydrosilane-Assisted Synthesis of Urea Derivatives from CO2 and Amines

	Hydrosilane-Assisted Synthesis of Urea Derivatives from CO2 and Amines
	Zhao, Yulei; Guo, Xuqiang; Si, Zhiyao; Hu, Yanan; Sun, Ying; Liu, Yunlin; Ji, Zhongyin; You, Jinmao
刊名	JOURNAL OF ORGANIC CHEMISTRY
	2020
卷号	85 期号:20
英文摘要	A methodology employing CO2, amines, and phenylsilane was discussed to access aryl- or alkyl-substituted urea derivatives. This procedure was characterized by adopting hydrosilane to promote the formation of ureas directly, without the need to prepare silylamines in advance. Control reactions suggested that FeCl3 was a favorable additive for the generation of ureas, and this 1,5,7-triazabicyclo[4.4.0] dec-5-ene-catalyzed reaction might proceed through nucleophilic addition, silicon migration, and the subsequent formal substitution of silylcarbamate.
内容类型	期刊论文
源URL	[http://210.75.249.4/handle/363003/60225]
专题	西北高原生物研究所_中国科学院西北高原生物研究所
推荐引用方式 GB/T 7714	Zhao, Yulei,Guo, Xuqiang,Si, Zhiyao,et al. Hydrosilane-Assisted Synthesis of Urea Derivatives from CO2 and Amines[J]. JOURNAL OF ORGANIC CHEMISTRY,2020,85(20).
APA	Zhao, Yulei.,Guo, Xuqiang.,Si, Zhiyao.,Hu, Yanan.,Sun, Ying.,...&You, Jinmao.(2020).Hydrosilane-Assisted Synthesis of Urea Derivatives from CO2 and Amines.JOURNAL OF ORGANIC CHEMISTRY,85(20).
MLA	Zhao, Yulei,et al."Hydrosilane-Assisted Synthesis of Urea Derivatives from CO2 and Amines".JOURNAL OF ORGANIC CHEMISTRY 85.20(2020).