Iron-modulated nickel cobalt phosphide embedded in carbon to boost power density of hybrid sodium-air battery

doi:10.1016/j.apcatb.2020.119786

CORC > 力学研究所 > 中国科学院力学研究所 > 高温气体动力学国家重点实验室

	Iron-modulated nickel cobalt phosphide embedded in carbon to boost power density of hybrid sodium-air battery
	Kang, Yao 7; Wang, Shuo 7; Zhu, Siqi 7; Gao, Haixing 7; Hui, Kwan San 8; Yuan, ChengZong 7; Yin, Hong 7; Bin F(宾峰)9; Wu, XiLin 1; Mai, Wenjie 2
刊名	APPLIED CATALYSIS B-ENVIRONMENTAL
	2021-05-15
卷号	285 页码:11
关键词	Iron doping Nickel cobalt phosphide Electronic structure reformation DFT calculation Hybrid sodium-air battery
ISSN号	0926-3373
DOI	10.1016/j.apcatb.2020.119786
通讯作者	Hui, Kwan San(k.hui@uea.ac.uk) ; Liang, Feng(liangfeng@kust.edu.cn) ; Chen, Fuming(fmchen@m.scnu.edu.cn) ; Hui, Kwun Nam(bizhui@um.edu.mo)
英文摘要	Nickel cobalt phosphide (NiCoP) is emerging as a potential electrocatalyst towards oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). However, its ORR/OER activities are sluggish. Here, we investigated the roles of iron dopants in the Fe-doped NiCoP (Fe-NiCoP) in order to boost its ORR/OER kinetics. The density functional theory (DFT) calculations reveal that the Fe dopant effectively modulates the electron conductivity of NiCoP and reduces binding energies of the reaction intermediates towards rate-determining steps of ORR and OER. A binder-free 3D microflowers morphology of the Fe-NiCoP embedded in the amorphous carbon layer (Fe-NiCoP@C) catalyst on the nickel foam was prepared as the air cathode for the hybrid sodium-air battery (HSAB). The HSAB displays a discharge voltage of 2.74 V at 0.01 mA cm(-2) with excellent round trip efficiency of 93.26 % at the 500th cycle and state-of-the-art power density of 621 mW g(-1).
分类号	一类
资助项目	Science and Technology Development Fund, Macau SAR[0191/2017/A3] ; Science and Technology Development Fund, Macau SAR[0041/2019/A1] ; Science and Technology Development Fund, Macau SAR[0046/2019/AFJ] ; Science and Technology Development Fund, Macau SAR[0021/2019/AIR] ; University of Macau[MYRG201700216-FST] ; University of Macau[MYRG2018-00192-IAPME] ; UEA ; Zhejiang Province Basic Public Welfare Research Project[LGF19B070006] ; Science and Technology Program of Guangzhou[2019050001] ; National Key Research and Development Program of China[2019YFE0198000] ; Pearl River Talent Program[2019QN01L951]
WOS研究方向	Chemistry ; Engineering
语种	英语
WOS记录号	WOS:000623240700002
资助机构	Science and Technology Development Fund, Macau SAR ; University of Macau ; UEA ; Zhejiang Province Basic Public Welfare Research Project ; Science and Technology Program of Guangzhou ; National Key Research and Development Program of China ; Pearl River Talent Program
其他责任者	Hui, Kwan San ; Liang, Feng ; Chen, Fuming ; Hui, Kwun Nam
内容类型	期刊论文
源URL	[http://dspace.imech.ac.cn/handle/311007/86139]
专题	力学研究所_高温气体动力学国家重点实验室
作者单位	1.Zhejiang Normal Univ, Coll Geog & Environm Sci, Jinhua 321004, Zhejiang, Peoples R China; 2.Jinan Univ, Dept Phys, Guangdong Prov Engn Technol Res Ctr Vacuum Coatin, Siyuan Lab, Guangzhou 510632, Peoples R China; 3.Shenzhen Univ, Coll Phys & Optoelect Engn, Nanhai Ave 3688, Shenzhen 518060, Guangdong, Peoples R China; 4.Jianghan Univ, Sch Chem & Environm Engn, Key Lab Optoelect Chem Mat & Devices, Minist Educ, Wuhan 430056, Peoples R China; 5.Kunming Univ Sci & Technol, State Key Lab Complex Nonferrous Met Resources Cl, Kunming 650093, Yunnan, Peoples R China; 6.South China Normal Univ, Sch Phys & Telecommun Engn, Guangdong Prov Key Lab Quantum Engn & Quantum Mat, Guangzhou 510006, Peoples R China 7.Univ Macau, Joint Key Lab Minist Educ, Inst Appl Phys & Mat Engn, Ave Univ, Taipa 999078, Macau, Peoples R China; 8.Univ East Anglia, Engn, Fac Sci, Norwich NR4 7TJ, Norfolk, England; 9.Chinese Acad Sci, Inst Mech, State Key Lab High Temp Gas Dynam, Beijing 100190, Peoples R China;
推荐引用方式 GB/T 7714	Kang, Yao,Wang, Shuo,Zhu, Siqi,et al. Iron-modulated nickel cobalt phosphide embedded in carbon to boost power density of hybrid sodium-air battery[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2021,285:11.
APA	Kang, Yao.,Wang, Shuo.,Zhu, Siqi.,Gao, Haixing.,Hui, Kwan San.,...&Hui, Kwun Nam.(2021).Iron-modulated nickel cobalt phosphide embedded in carbon to boost power density of hybrid sodium-air battery.APPLIED CATALYSIS B-ENVIRONMENTAL,285,11.
MLA	Kang, Yao,et al."Iron-modulated nickel cobalt phosphide embedded in carbon to boost power density of hybrid sodium-air battery".APPLIED CATALYSIS B-ENVIRONMENTAL 285(2021):11.