Ionic-Liquid-Modified Porous Au/CeMnOx Nanorods for Methyl Methacrylate (MMA) Synthesis via Direct Oxidative Esterification

doi:10.1002/cnma.201900408

	Ionic-Liquid-Modified Porous Au/CeMnOx Nanorods for Methyl Methacrylate (MMA) Synthesis via Direct Oxidative Esterification
	Tian, Yun 2; Li, Yuchao 1,2; Zuo, Cuncun 2; Yin, Defeng 2; Wang, Ling 3; Zheng, Yanxia 2; Huang, Haofei 2; Fu, Zhongjun 2; Wang, Ming 2
刊名	CHEMNANOMAT
	2019-09-27
页码	7
关键词	Porous MnCeOx Ionic liquids Nano-Au Methyl methacrylate Oxidative esterification
ISSN号	2199-692X
DOI	10.1002/cnma.201900408
英文摘要	Porous MnCeOx solid solutions nanorods (PN-MnCeOx) with different pore sizes were prepared using different carbon chain lengths ionic liquids (C(10)mimCl, C(12)mimCl and C(14)mimCl). Series of novel catalysts with nano-Au supported on the PN-MnCeOx, were synthesized and applied to oxidative esterification of aldehydes (benzaldehyde derivatives or methacrolein - MAL) to esters. Catalytic performance was evaluated in batch reactor and the relatively optimum catalyst was screened out. Kinds of characterization methods, such as XRD, TEM, XPS and BET, were applied to analyze crystal plane, microstructure, specific surface area, and porous structure of the catalysts and the structure-activity relationship could be reasonably explained. The cyclic stability of the catalyst was also tested more than 7 times using MAL and methanol for methyl methacrylate synthesis via one step oxidative esterification.
资助项目	Natural Science Foundation of China[21706149] ; Shandong Provincial Natural Science Foundation[ZR2017BB079]
WOS关键词	GOLD NANOPARTICLES ; CO OXIDATION ; AEROBIC OXIDATION ; CATALYSTS ; DEACTIVATION ; AU ; METHACROLEIN ; ALDEHYDES ; ALCOHOLS ; OXIDES
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000487833700001
资助机构	Natural Science Foundation of China ; Shandong Provincial Natural Science Foundation
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/30858]
专题	中国科学院过程工程研究所
通讯作者	Li, Yuchao
作者单位	1.266 Xincun West Rd, Zhangdian Dist 255000, Zibo, Peoples R China 2.Shandong Univ Technol, Sch Chem & Chem Engn, Zibo 255049, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Tian, Yun,Li, Yuchao,Zuo, Cuncun,et al. Ionic-Liquid-Modified Porous Au/CeMnOx Nanorods for Methyl Methacrylate (MMA) Synthesis via Direct Oxidative Esterification[J]. CHEMNANOMAT,2019:7.
APA	Tian, Yun.,Li, Yuchao.,Zuo, Cuncun.,Yin, Defeng.,Wang, Ling.,...&Wang, Ming.(2019).Ionic-Liquid-Modified Porous Au/CeMnOx Nanorods for Methyl Methacrylate (MMA) Synthesis via Direct Oxidative Esterification.CHEMNANOMAT,7.
MLA	Tian, Yun,et al."Ionic-Liquid-Modified Porous Au/CeMnOx Nanorods for Methyl Methacrylate (MMA) Synthesis via Direct Oxidative Esterification".CHEMNANOMAT (2019):7.