Pd-Catalyzed Acetoxylation of gamma-C(sp(3))-H Bonds of Amines Directed by a Removable Bts-Protecting Group | |
Zheng, Yong; Song, Weibin; Zhu, Yefu; Wei, Bole; Xuan, Lijiang | |
刊名 | JOURNAL OF ORGANIC CHEMISTRY |
2018-02-16 | |
卷号 | 83期号:4页码:2448-2454 |
ISSN号 | 0022-3263 |
DOI | 10.1021/acs.joc.7b02995 |
文献子类 | Article |
英文摘要 | Pd-catalyzed acetoxylation of gamma-C(sp(3))-H bonds directed by Bts-protected amines using inexpensive PhI(OAc)(2) as oxidant is reported. The Bts-protecting group is easily introduced and removed under mild conditions. This protocol provides an important strategy for the construction of gamma-hydroxyl amine derivatives. |
资助项目 | National Natural Science Foundation of China[81602995] |
WOS关键词 | C-H ACTIVATION ; NATIVE CHEMICAL LIGATION ; CARBON-HYDROGEN BONDS ; EFFICIENT SYNTHESES ; ACID-DERIVATIVES ; FUNCTIONALIZATION ; C(SP(3))-H ; C(SP(2))-H ; INHIBITOR ; AUXILIARY |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000427094200081 |
内容类型 | 期刊论文 |
源URL | [http://119.78.100.183/handle/2S10ELR8/279897] |
专题 | 上海中药现代化研究中心 中科院受体结构与功能重点实验室 新药研究国家重点实验室 |
通讯作者 | Xuan, Lijiang |
作者单位 | Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, 501 Haike Rd, Shanghai 201203, Peoples R China |
推荐引用方式 GB/T 7714 | Zheng, Yong,Song, Weibin,Zhu, Yefu,et al. Pd-Catalyzed Acetoxylation of gamma-C(sp(3))-H Bonds of Amines Directed by a Removable Bts-Protecting Group[J]. JOURNAL OF ORGANIC CHEMISTRY,2018,83(4):2448-2454. |
APA | Zheng, Yong,Song, Weibin,Zhu, Yefu,Wei, Bole,&Xuan, Lijiang.(2018).Pd-Catalyzed Acetoxylation of gamma-C(sp(3))-H Bonds of Amines Directed by a Removable Bts-Protecting Group.JOURNAL OF ORGANIC CHEMISTRY,83(4),2448-2454. |
MLA | Zheng, Yong,et al."Pd-Catalyzed Acetoxylation of gamma-C(sp(3))-H Bonds of Amines Directed by a Removable Bts-Protecting Group".JOURNAL OF ORGANIC CHEMISTRY 83.4(2018):2448-2454. |
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