A novel electrochemiluminescence system of CuS film and K2S2O8 for determination of crystal violet

doi:10.1016/j.jelechem.2018.01.008

	A novel electrochemiluminescence system of CuS film and K2S2O8 for determination of crystal violet
	Lan, Qiufeng 3; Li, Qingyi 2; Zhang, Xueyan 1; Chen, Zhidong 3
刊名	JOURNAL OF ELECTROANALYTICAL CHEMISTRY
	2018-02-01
卷号	810 页码:216-221
关键词	Electrochemiluminescence Electrodeposition CuS film K2S2O8 Crystal violet
ISSN号	1572-6657
DOI	10.1016/j.jelechem.2018.01.008
文献子类	Article
英文摘要	A novel electrochemiluminescence (ECL) system that consists of the copper sulphide (CuS) film and K2S2O8 was prepared and used for detecting crystal violet in aqueous solutions. The CuS film was a luminescent semiconductor material, which was modified on glassy carbon electrode (GCE) via one-step electro-deposition. To enhance the ECL intensity, K2S2O8 was added into the solution. The morphology and composition of the modified electrodes were analyzed with scanning electron microscope, energy-dispersed spectrum, transmission electron microscope, high resolution transmission electron microscopy, X-ray diffraction and Raman spectroscopy. Electrochemical impedance spectroscopy (EIS) was studied for different electrodeposition time. Under the optimal conditions, the ECL intensity of the quenching value (Delta ECL) versus the logarithm of the concentration of crystal violet was linear over a concentration range from 5.0 x 10(-8) to 1.0 x 10(-5) mol L-1 (r = 0.9926) and the limit of detection (LOD) was up to 3.2 x 10(-9) mol L-1.
资助项目	National Natural Science Foundation of China[51574047] ; Natural Science Foundation of the Jiangsu Higher Education Institutions of China[16KJA430004]
WOS关键词	THIN-FILM ; ELECTROGENERATED CHEMILUMINESCENCE ; SPECTROPHOTOMETRIC DETERMINATION ; AQUEOUS-SOLUTION ; MALACHITE GREEN ; QUANTUM DOTS ; BIOSENSOR ; DEPOSITION ; ELECTRODE ; WATER
WOS研究方向	Chemistry ; Electrochemistry
语种	英语
出版者	ELSEVIER SCIENCE SA
WOS记录号	WOS:000425560800028
内容类型	期刊论文
源URL	[http://119.78.100.183/handle/2S10ELR8/279924]
专题	中国科学院上海药物研究所
通讯作者	Chen, Zhidong
作者单位	1.Nanjing Forestry Univ, Major Chem Engn & Technol, Nanjing 210000, Jiangsu, Peoples R China 2.Changzhou SIMM DRUG R&D Co Ltd, Changzhou 213164, Peoples R China; 3.Changzhou Univ, Sch Petrochem Engn, Changzhou 213164, Peoples R China;
推荐引用方式 GB/T 7714	Lan, Qiufeng,Li, Qingyi,Zhang, Xueyan,et al. A novel electrochemiluminescence system of CuS film and K2S2O8 for determination of crystal violet[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY,2018,810:216-221.
APA	Lan, Qiufeng,Li, Qingyi,Zhang, Xueyan,&Chen, Zhidong.(2018).A novel electrochemiluminescence system of CuS film and K2S2O8 for determination of crystal violet.JOURNAL OF ELECTROANALYTICAL CHEMISTRY,810,216-221.
MLA	Lan, Qiufeng,et al."A novel electrochemiluminescence system of CuS film and K2S2O8 for determination of crystal violet".JOURNAL OF ELECTROANALYTICAL CHEMISTRY 810(2018):216-221.