Synthesis, crystal structures and optical properties of noncentrosymmetric oxysulfides AeGeS(2)O (Ae = Sr, Ba) | |
Zhang, Xian; Xiao, Yi; Wang, Ruico; Fu, Pengxiang; Zheng, Chong; Huang, Fudiang | |
刊名 | DALTON TRANSACTIONS |
2019-10-21 | |
卷号 | 48期号:39页码:14662 |
ISSN号 | 1477-9226 |
DOI | 10.1039/c9dt02780g |
文献子类 | Article |
英文摘要 | Two new oxysulfides, AeGeS(2)O (Ae = Sr, Ba), were successfully synthesized via the molten salt method. The two isostructural compounds crystallize in the noncentrosymmetric space group P2(1)2(1)2(1). Their structures feature 1 infinity[GeS2O](2-) one-dimensional helical chains which are built up by [GeS2O2](4-) heteroanionic tetrahedra via corner sharing of O atoms. The two oxysulfides are typical semiconductors with wide bandgaps (SrGeS2O: 3.9 eV and BaGeS2O: 4.1 eV) that are perfectly consistent with the first-principles calculation results. They show typical band emissions under UV light excitation (SrGeS2O: 375 nm and BaGeS2O: 360 nm). In addition, SrGeS2O also possesses an orange-yellow light emission (572 nm). SrGeS2O and BaGeS2O exhibit moderate second harmonic generation (SHG) intensities of 0.4 x AgGaS2 and 0.5 x AgGaS2, respectively. |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
内容类型 | 期刊论文 |
源URL | [http://ir.sic.ac.cn/handle/331005/26770] |
专题 | 中国科学院上海硅酸盐研究所 |
推荐引用方式 GB/T 7714 | Zhang, Xian,Xiao, Yi,Wang, Ruico,et al. Synthesis, crystal structures and optical properties of noncentrosymmetric oxysulfides AeGeS(2)O (Ae = Sr, Ba)[J]. DALTON TRANSACTIONS,2019,48(39):14662. |
APA | Zhang, Xian,Xiao, Yi,Wang, Ruico,Fu, Pengxiang,Zheng, Chong,&Huang, Fudiang.(2019).Synthesis, crystal structures and optical properties of noncentrosymmetric oxysulfides AeGeS(2)O (Ae = Sr, Ba).DALTON TRANSACTIONS,48(39),14662. |
MLA | Zhang, Xian,et al."Synthesis, crystal structures and optical properties of noncentrosymmetric oxysulfides AeGeS(2)O (Ae = Sr, Ba)".DALTON TRANSACTIONS 48.39(2019):14662. |
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