Electrochemical and Spectroscopic Study of Homo- and Hetero-Dimetallic Phthalocyanines as Catalysts for the Oxygen Reduction Reaction in Acidic Media

doi:10.1002/celc.201800977

CORC > 上海应用物理研究所 > 中国科学院上海应用物理研究所 > 中科院上海应用物理研究所2011-2017年

	Electrochemical and Spectroscopic Study of Homo- and Hetero-Dimetallic Phthalocyanines as Catalysts for the Oxygen Reduction Reaction in Acidic Media
	Wang, XJ ; Liu, Y ; Wang, Y ; Ren, R ; Chen, HQ ; Jiang, Z ; He, QG
刊名	CHEMELECTROCHEM
	2018
卷号	5 期号:22 页码:3478-3485
关键词	4-ELECTRON REDUCTION FUEL-CELL ELECTROCATALYSTS FE PORPHYRINS WATER MN CO
ISSN号	2196-0216
DOI	10.1002/celc.201800977
文献子类	期刊论文
英文摘要	Metallophthalocyanines (MPc, M=Fe or Co) have been investigated extensively as a typical type of transition metal macrocyclic catalysts for the oxygen reduction reaction (ORR). However, the understanding about ORR catalyzed by binuclear even heterodimetallic phthalocyanines in acidic condition is still not sufficient. Herein we synthesized two homodimetallicphthalocyanine (FePc-PcFe and CoPc-PcCo) and a heterodimetallic phthalocyanine (FePc-PcCo). The electrocatalytic activity of as-synthesized compounds were characterized by cyclic voltammetry (CV) and rotating disk electrode (RDE). Generally, the binuclear metallophthalocyanines show higher activity than their monomeric analogues including FePc and CoPc. Also, the Fe compounds exhibit better catalytic performance than the Co phthalocyanines. However, interestingly the heterodimetallic phthalocyanine FePc-PcCo shows similar half-wave potential and ORR activity with FePc-PcFe, rather than CoPc-PcCo. This may be explained by XPS and XAS, which reveal a similar square-planar structure existed in FePc-PcCo and FePc-PcFe and a non-planar structure in CoPc-PcCo. Furthermore, the increasing of the ORR activity among those five catalysts is well in agreement with the descending LUMO energies in DFT calculations. A lower LUMO energy indicates a favorable adsorption of O-2, which in turn affects the ORR performance.
语种	英语
内容类型	期刊论文
源URL	[http://ir.sinap.ac.cn/handle/331007/30926]
专题	上海应用物理研究所_中科院上海应用物理研究所2011-2017年
作者单位	1.KTH Royal Inst Technol, Sch Biotechnol, Div Theoret Chem & Biol, S-10691 Stockholm, Sweden 2.Zhejiang Univ, Zhejiang Prov Key Lab Adv Chem Engn Mfg Technol, Coll Chem & Biol Engn, Hangzhou 310027, Zhejiang, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China
推荐引用方式 GB/T 7714	Wang, XJ,Liu, Y,Wang, Y,et al. Electrochemical and Spectroscopic Study of Homo- and Hetero-Dimetallic Phthalocyanines as Catalysts for the Oxygen Reduction Reaction in Acidic Media[J]. CHEMELECTROCHEM,2018,5(22):3478-3485.
APA	Wang, XJ.,Liu, Y.,Wang, Y.,Ren, R.,Chen, HQ.,...&He, QG.(2018).Electrochemical and Spectroscopic Study of Homo- and Hetero-Dimetallic Phthalocyanines as Catalysts for the Oxygen Reduction Reaction in Acidic Media.CHEMELECTROCHEM,5(22),3478-3485.
MLA	Wang, XJ,et al."Electrochemical and Spectroscopic Study of Homo- and Hetero-Dimetallic Phthalocyanines as Catalysts for the Oxygen Reduction Reaction in Acidic Media".CHEMELECTROCHEM 5.22(2018):3478-3485.