CdS/CdSe quantum dot co-sensitized graphene nanocomposites via polymer brush templated synthesis for potential photovoltaic applications
Yan JF(严俊峰)1,2; Ye Q(叶谦)1; Wang XL(王晓龙)1; Yu B(于波)1; Zhou F(周峰)1; Zhou F(周峰); Ye Q(叶谦)
刊名Nanoscale
2012
卷号4期号:6页码:2109-2116
ISSN号2040-3364
通讯作者叶谦 ; 周峰
英文摘要CdS/CdSe quantum dot (QDs) co-sensitized graphene sheets have been obtained via polymer brush templated synthesis. Firstly, the anionic functional polymer (polymethacrylate cadmium) was grafted via the surface initiated atomic transfer radical polymerization (ATRP) using a macromolecular initiator, which contains polymerized pyrene units for chemical anchoring on graphene surface and alkyl bromines to initiate ATRP. Then, the coordinated cadmium in the polymer chains can act as a source precursor for QDs. After reaction, polymer brushes can be recovered and act as the nanoreactor via the absorption of cadmium ions by carboxylate groups. So, high density QDs can be multiply uploaded onto the graphene surface by repeated steps. The as-prepared composite materials exhibited significantly enhanced visible light response compared to plain graphene, and have potential applications as the platform to build solar cell assembles.
学科主题材料科学与物理化学
收录类别SCI
资助信息NSFC (20973188;21125316);the “Hundred Talents Program” of Chinese Academy of Sciences
语种英语
WOS记录号WOS:000301000900032
公开日期2013-07-12
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/3419]  
专题兰州化学物理研究所_固体润滑国家重点实验室
通讯作者Zhou F(周峰); Ye Q(叶谦)
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Yan JF,Ye Q,Wang XL,et al. CdS/CdSe quantum dot co-sensitized graphene nanocomposites via polymer brush templated synthesis for potential photovoltaic applications[J]. Nanoscale,2012,4(6):2109-2116.
APA Yan JF.,Ye Q.,Wang XL.,Yu B.,Zhou F.,...&叶谦.(2012).CdS/CdSe quantum dot co-sensitized graphene nanocomposites via polymer brush templated synthesis for potential photovoltaic applications.Nanoscale,4(6),2109-2116.
MLA Yan JF,et al."CdS/CdSe quantum dot co-sensitized graphene nanocomposites via polymer brush templated synthesis for potential photovoltaic applications".Nanoscale 4.6(2012):2109-2116.
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