CdS/CdSe quantum dot co-sensitized graphene nanocomposites via polymer brush templated synthesis for potential photovoltaic applications | |
Yan JF(严俊峰)1,2; Ye Q(叶谦)1; Wang XL(王晓龙)1; Yu B(于波)1; Zhou F(周峰)1; Zhou F(周峰); Ye Q(叶谦) | |
刊名 | Nanoscale |
2012 | |
卷号 | 4期号:6页码:2109-2116 |
ISSN号 | 2040-3364 |
通讯作者 | 叶谦 ; 周峰 |
英文摘要 | CdS/CdSe quantum dot (QDs) co-sensitized graphene sheets have been obtained via polymer brush templated synthesis. Firstly, the anionic functional polymer (polymethacrylate cadmium) was grafted via the surface initiated atomic transfer radical polymerization (ATRP) using a macromolecular initiator, which contains polymerized pyrene units for chemical anchoring on graphene surface and alkyl bromines to initiate ATRP. Then, the coordinated cadmium in the polymer chains can act as a source precursor for QDs. After reaction, polymer brushes can be recovered and act as the nanoreactor via the absorption of cadmium ions by carboxylate groups. So, high density QDs can be multiply uploaded onto the graphene surface by repeated steps. The as-prepared composite materials exhibited significantly enhanced visible light response compared to plain graphene, and have potential applications as the platform to build solar cell assembles. |
学科主题 | 材料科学与物理化学 |
收录类别 | SCI |
资助信息 | NSFC (20973188;21125316);the “Hundred Talents Program” of Chinese Academy of Sciences |
语种 | 英语 |
WOS记录号 | WOS:000301000900032 |
公开日期 | 2013-07-12 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/3419] |
专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
通讯作者 | Zhou F(周峰); Ye Q(叶谦) |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Yan JF,Ye Q,Wang XL,et al. CdS/CdSe quantum dot co-sensitized graphene nanocomposites via polymer brush templated synthesis for potential photovoltaic applications[J]. Nanoscale,2012,4(6):2109-2116. |
APA | Yan JF.,Ye Q.,Wang XL.,Yu B.,Zhou F.,...&叶谦.(2012).CdS/CdSe quantum dot co-sensitized graphene nanocomposites via polymer brush templated synthesis for potential photovoltaic applications.Nanoscale,4(6),2109-2116. |
MLA | Yan JF,et al."CdS/CdSe quantum dot co-sensitized graphene nanocomposites via polymer brush templated synthesis for potential photovoltaic applications".Nanoscale 4.6(2012):2109-2116. |
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