Dinuclear Iron Complex-Catalyzed Cross-Coupling of Primary Alkyl Fluorides with Aryl Grignard Reagents

CORC > 上海有机化学研究所 > 中国科学院上海有机化学研究所 > 金属有机化学国家重点实验室

	Dinuclear Iron Complex-Catalyzed Cross-Coupling of Primary Alkyl Fluorides with Aryl Grignard Reagents
	Mo ZB(莫贞波) ; Zhang Q(张强) ; Deng L(邓亮)
刊名	Organometallics
	2012
卷号	31 期号:18 页码:6518-6521
ISSN号	0276-7333
其他题名	铁催化的C(sp3)-F键的芳基化反应
通讯作者	邓亮
英文摘要	Iron-catalyzed cross-coupling of nonactivated primary alkyl fluorides with aryl Grignard reagents has been achieved by using the low-coordinate dinuclear iron complex [(IPr2Me2)Fe(mu(2)-NDipp)(2)Fe(IPr2Me2)] as the catalyst. This iron-catalyzed C(sp(3))-F bond arylation reaction is applicable to a variety of aryl Grignard reagents and primary alkyl fluorides. The product pattern suggests the involvement of a radical-type mechanism for its C-F bond scission step.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/om300722g
语种	英语
WOS记录号	WOS:000309022700003
公开日期	2013-08-22
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/28129]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Mo ZB,Zhang Q,Deng L. Dinuclear Iron Complex-Catalyzed Cross-Coupling of Primary Alkyl Fluorides with Aryl Grignard Reagents[J]. Organometallics,2012,31(18):6518-6521.
APA	莫贞波,张强,&邓亮.(2012).Dinuclear Iron Complex-Catalyzed Cross-Coupling of Primary Alkyl Fluorides with Aryl Grignard Reagents.Organometallics,31(18),6518-6521.
MLA	莫贞波,et al."Dinuclear Iron Complex-Catalyzed Cross-Coupling of Primary Alkyl Fluorides with Aryl Grignard Reagents".Organometallics 31.18(2012):6518-6521.