A Co-Fe Prussian blue analogue for efficient Fenton-like catalysis: the effect of high-spin cobalt

doi:10.1039/c9cc01872g

	A Co-Fe Prussian blue analogue for efficient Fenton-like catalysis: the effect of high-spin cobalt
	Zhao, Chunxiao 2,4; Liu, Biao 3; Li, Xuning 1; Zhu, Kaixin 2; Hu, Ruisheng 4; Ao, Zhimin 3; Wang, Junhu 2
刊名	CHEMICAL COMMUNICATIONS
	2019-06-25
卷号	55 期号:50 页码:7151-7154
ISSN号	1359-7345
DOI	10.1039/c9cc01872g
通讯作者	Ao, Zhimin(zhimin.ao@gdut.edu.cn) ; Wang, Junhu(wangjh@dicp.ac.cn)
英文摘要	Herein, we, for the first time, report a high spin Co-Fe Prussian blue analogue (Co-Fe PBA) as a highly efficient Fenton-like catalyst for sulfate radical (SO4 center dot-) production. Our experiments and density functional theory (DFT) calculations show that the largely elongated SO4-OH bond length, strengthened adsorption and facilitated electron transfer for peroxymonosulfate (PMS) activation catalyzed by high-spin (HS) CoII are the main factors contributing to its excellent activity.
资助项目	National Natural Science Foundation of China[21476232] ; National Natural Science Foundation of China[21607029] ; National Natural Science Foundation of China[21777033] ; International Partnership Program of Chinese Academy of Sciences[121421KYSB20170020] ; State Key Laboratory of Catalysis in the Dalian Institute of Chemical Physics[N-16-07] ; Science and Technology Program of Guangdong Province[2017B020216003] ; Science and Technology Program of Guangzhou City[201707010359] ; National Supercomputing Centre in Guangzhou (NSCCGZ) ; 1000 Plan Program for Young Professionals of China ; 100 Talents Program of Guangdong University of Technology
WOS关键词	HYDROXYL RADICALS ; BISPHENOL-A ; DEGRADATION ; ACTIVATION ; PEROXYMONOSULFATE ; SPECTROSCOPY ; OXIDATION ; REMOVAL ; PH
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000471909900030
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; International Partnership Program of Chinese Academy of Sciences ; International Partnership Program of Chinese Academy of Sciences ; State Key Laboratory of Catalysis in the Dalian Institute of Chemical Physics ; State Key Laboratory of Catalysis in the Dalian Institute of Chemical Physics ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou City ; Science and Technology Program of Guangzhou City ; National Supercomputing Centre in Guangzhou (NSCCGZ) ; National Supercomputing Centre in Guangzhou (NSCCGZ) ; 1000 Plan Program for Young Professionals of China ; 1000 Plan Program for Young Professionals of China ; 100 Talents Program of Guangdong University of Technology ; 100 Talents Program of Guangdong University of Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; International Partnership Program of Chinese Academy of Sciences ; International Partnership Program of Chinese Academy of Sciences ; State Key Laboratory of Catalysis in the Dalian Institute of Chemical Physics ; State Key Laboratory of Catalysis in the Dalian Institute of Chemical Physics ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou City ; Science and Technology Program of Guangzhou City ; National Supercomputing Centre in Guangzhou (NSCCGZ) ; National Supercomputing Centre in Guangzhou (NSCCGZ) ; 1000 Plan Program for Young Professionals of China ; 1000 Plan Program for Young Professionals of China ; 100 Talents Program of Guangdong University of Technology ; 100 Talents Program of Guangdong University of Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; International Partnership Program of Chinese Academy of Sciences ; International Partnership Program of Chinese Academy of Sciences ; State Key Laboratory of Catalysis in the Dalian Institute of Chemical Physics ; State Key Laboratory of Catalysis in the Dalian Institute of Chemical Physics ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou City ; Science and Technology Program of Guangzhou City ; National Supercomputing Centre in Guangzhou (NSCCGZ) ; National Supercomputing Centre in Guangzhou (NSCCGZ) ; 1000 Plan Program for Young Professionals of China ; 1000 Plan Program for Young Professionals of China ; 100 Talents Program of Guangdong University of Technology ; 100 Talents Program of Guangdong University of Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; International Partnership Program of Chinese Academy of Sciences ; International Partnership Program of Chinese Academy of Sciences ; State Key Laboratory of Catalysis in the Dalian Institute of Chemical Physics ; State Key Laboratory of Catalysis in the Dalian Institute of Chemical Physics ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou City ; Science and Technology Program of Guangzhou City ; National Supercomputing Centre in Guangzhou (NSCCGZ) ; National Supercomputing Centre in Guangzhou (NSCCGZ) ; 1000 Plan Program for Young Professionals of China ; 1000 Plan Program for Young Professionals of China ; 100 Talents Program of Guangdong University of Technology ; 100 Talents Program of Guangdong University of Technology
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/175824]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Ao, Zhimin; Wang, Junhu
作者单位	1.Nanyang Technol Univ, Sch Chem & Biomed Engn, 62 Nanyang Dr, Singapore 637459, Singapore 2.Chinese Acad Sci, Dalian Inst Chem Phys, Mossbauer Effect Data Ctr, Dalian 116023, Peoples R China 3.Guangdong Univ Technol, Sch Environm Sci & Engn, Inst Environm Hlth & Pollut Control, Guangzhou 510006, Guangdong, Peoples R China 4.Inner Mongolia Univ, Coll Chem & Chem Engn, Hohhot 010021, Peoples R China
推荐引用方式 GB/T 7714	Zhao, Chunxiao,Liu, Biao,Li, Xuning,et al. A Co-Fe Prussian blue analogue for efficient Fenton-like catalysis: the effect of high-spin cobalt[J]. CHEMICAL COMMUNICATIONS,2019,55(50):7151-7154.
APA	Zhao, Chunxiao.,Liu, Biao.,Li, Xuning.,Zhu, Kaixin.,Hu, Ruisheng.,...&Wang, Junhu.(2019).A Co-Fe Prussian blue analogue for efficient Fenton-like catalysis: the effect of high-spin cobalt.CHEMICAL COMMUNICATIONS,55(50),7151-7154.
MLA	Zhao, Chunxiao,et al."A Co-Fe Prussian blue analogue for efficient Fenton-like catalysis: the effect of high-spin cobalt".CHEMICAL COMMUNICATIONS 55.50(2019):7151-7154.