Visible-light-driven coproduction of diesel precursors and hydrogen from lignocellulose-derived methylfurans

doi:10.1038/s41560-019-0403-5

	Visible-light-driven coproduction of diesel precursors and hydrogen from lignocellulose-derived methylfurans
	Luo, Nengchao 1,2; Montini, Tiziano 3; Zhang, Jian 1; Fornasiero, Paolo 3; Fonda, Emiliano 4; Hou, Tingting 1,2; Nie, Wei 1,2; Lu, Jianmin 1; Liu, Junxue 5,6; Heggen, Marc 7,8
刊名	NATURE ENERGY
	2019-07-01
卷号	4 期号:7 页码:575-584
ISSN号	2058-7546
DOI	10.1038/s41560-019-0403-5
通讯作者	Wang, Feng(wangfeng@dicp.ac.cn)
英文摘要	Photocatalytic hydrogen production from biomass is a promising alternative to water splitting thanks to the oxidation half-reaction being more facile and its ability to simultaneously produce solar fuels and value-added chemicals. Here, we demonstrate the coproduction of H-2 and diesel fuel precursors from lignocellulose-derived methylfurans via acceptorless dehydrogenative C-C coupling, using a Ru-doped ZnIn2S4 catalyst and driven by visible light. With this chemistry, up to 1.04 g g(catalyst)(-1)h(-1) of diesel fuel precursors (similar to 41% of which are precursors of branched-chain alkanes) are produced with selectivity higher than 96%, together with 6.0 mmol g(catalyst)(-1) h(-1) of H-2. Subsequent hydrodeoxygenation reactions yield the desired diesel fuels comprising straight- and branched-chain alkanes. We suggest that Ru dopants, substituted in the position of indium ions in the ZnIn2S4 matrix, improve charge separation efficiency, thereby accelerating C-H activation for the coproduction of H-2 and diesel fuel precursors.
资助项目	National Natural Science Foundation of China[21721004] ; National Natural Science Foundation of China[21690082] ; National Natural Science Foundation of China[21690084] ; National Natural Science Foundation of China[21690080] ; National Natural Science Foundation of China[21711530020] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDB17020300] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDB17000000] ; University of Trieste (programme FRA 2018, project INSIDE) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; INSTM consortium
WOS关键词	HIGH-QUALITY DIESEL ; CATALYTIC CONVERSION ; EFFICIENT SYNTHESIS ; LIQUID ALKANES ; LIGNIN MODELS ; PLATFORM ; 2,5-DIMETHYLFURAN ; NANOPARTICLES ; 2-METHYLFURAN ; CHEMICALS
WOS研究方向	Energy & Fuels ; Materials Science
语种	英语
出版者	NATURE PUBLISHING GROUP
WOS记录号	WOS:000474920100014
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; University of Trieste (programme FRA 2018, project INSIDE) ; University of Trieste (programme FRA 2018, project INSIDE) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; INSTM consortium ; INSTM consortium ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; University of Trieste (programme FRA 2018, project INSIDE) ; University of Trieste (programme FRA 2018, project INSIDE) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; INSTM consortium ; INSTM consortium ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; University of Trieste (programme FRA 2018, project INSIDE) ; University of Trieste (programme FRA 2018, project INSIDE) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; INSTM consortium ; INSTM consortium ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; University of Trieste (programme FRA 2018, project INSIDE) ; University of Trieste (programme FRA 2018, project INSIDE) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; Italian Ministry for University and Research (MIUR, programme FFABR 2017) ; INSTM consortium ; INSTM consortium
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/175174]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Wang, Feng
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian, Peoples R China 2.Univ Chinese Acad Sci, Beijing, Peoples R China 3.Univ Trieste, Dept Chem & Pharmaceut Sci, INSTM Res Unit, ICCOM CNR Trieste Res Unit, Trieste, Italy 4.Synchrotron SOLEIL, Paris, France 5.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian, Peoples R China 6.Chinese Acad Sci, Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian Inst Chem Phys, Dalian, Peoples R China 7.Forschungszentrum Julich, Ernst Ruska Ctr Microscopy & Spect Electron, Julich, Germany 8.Forschungszentrum Julich, Peter Grunberg Inst, Julich, Germany
推荐引用方式 GB/T 7714	Luo, Nengchao,Montini, Tiziano,Zhang, Jian,et al. Visible-light-driven coproduction of diesel precursors and hydrogen from lignocellulose-derived methylfurans[J]. NATURE ENERGY,2019,4(7):575-584.
APA	Luo, Nengchao.,Montini, Tiziano.,Zhang, Jian.,Fornasiero, Paolo.,Fonda, Emiliano.,...&Wang, Feng.(2019).Visible-light-driven coproduction of diesel precursors and hydrogen from lignocellulose-derived methylfurans.NATURE ENERGY,4(7),575-584.
MLA	Luo, Nengchao,et al."Visible-light-driven coproduction of diesel precursors and hydrogen from lignocellulose-derived methylfurans".NATURE ENERGY 4.7(2019):575-584.