Decorated Traditional Zeolites with Subunits of Metal-Organic Frameworks for CH4/N-2 Separation

doi:10.1002/anie.201905014

	Decorated Traditional Zeolites with Subunits of Metal-Organic Frameworks for CH4/N-2 Separation
	Wu, Yaqi 1,2; Yuan, Danhua 2; He, Dawei 1,2; Xing, Jiacheng 1,2; Zeng, Shu 1,2; Xu, Shutao 2; Xu, Yunpeng 2; Liu, Zhongmin 2
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2019-07-22
卷号	58 期号:30 页码:10241-10244
关键词	gas adsorption metal-organic frameworks surface decoration zeolites
ISSN号	1433-7851
DOI	10.1002/anie.201905014
通讯作者	Xu, Yunpeng(xuyp@dicp.ac.cn) ; Liu, Zhongmin(liuzm@dicp.ac.cn)
英文摘要	Metal-organic frameworks (MOF) materials are promising materials for gas separation, but their application still faces various challenges. A strategy is now reported for introducing subunits of MOFs into traditional zeolite frameworks to obtain applicable adsorbents with advantages of both zeolites and MOFs. The subunits of ZIFs were introduced into zeolite Y and zeolite ZSM-5 for CH4/N-2 separation. Both the molecular simulation and experimental results validated that the IAST CH4/N-2 selectivity of the resulting samples greatly improved (above 8, at 100 kPa and 25 degrees C) with the incorporation of ZIF subunits into zeolites structure, and the selectivities were obviously higher than that of zeolites and even better than that of ZIFs. This strategy not only gave rise to an efficient adsorbent for CH4/N-2 separation but also provided ideas for design of other adsorption and separation materials.
资助项目	National Key Research and Development Program of China[2016YFB0301603]
WOS关键词	IMIDAZOLATE FRAMEWORKS ; NMR ; ADSORPTION ; ZIF-8 ; CO2 ; TEMPERATURE ; MEMBRANES ; MOBILITY ; DESIGN ; XENON
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000476452700032
资助机构	National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/173968]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Xu, Yunpeng; Liu, Zhongmin
作者单位	1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Lab Methanol Olefins, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Wu, Yaqi,Yuan, Danhua,He, Dawei,et al. Decorated Traditional Zeolites with Subunits of Metal-Organic Frameworks for CH4/N-2 Separation[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019,58(30):10241-10244.
APA	Wu, Yaqi.,Yuan, Danhua.,He, Dawei.,Xing, Jiacheng.,Zeng, Shu.,...&Liu, Zhongmin.(2019).Decorated Traditional Zeolites with Subunits of Metal-Organic Frameworks for CH4/N-2 Separation.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,58(30),10241-10244.
MLA	Wu, Yaqi,et al."Decorated Traditional Zeolites with Subunits of Metal-Organic Frameworks for CH4/N-2 Separation".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 58.30(2019):10241-10244.