Potassium tert-Butoxide-Promoted Acceptorless Dehydrogenation of N-Heterocycles

doi:10.1002/adsc.201900499

	Potassium tert-Butoxide-Promoted Acceptorless Dehydrogenation of N-Heterocycles
	Liu, Tingting 2,3,4; Wu, Kaikai 2; Wang, Liandi 2; Yu, Zhengkun 1,2
刊名	ADVANCED SYNTHESIS & CATALYSIS
	2019-07-16
页码	8
关键词	acceptorless dehydrogenation N-heterocycles potassium tert-butoxide transition-metal-free dihydrogen
ISSN号	1615-4150
DOI	10.1002/adsc.201900499
通讯作者	Yu, Zhengkun(zkyu@dicp.ac.cn)
英文摘要	Potassium tert-butoxide-promoted acceptorless dehydrogenation of N-heterocycles was efficiently realized for the generation of N-heteroarenes and hydrogen gas under transition-metal-free conditions. In the presence of KOtBu base, a variety of six- and five-membered N-heterocyclic compounds efficiently underwent acceptorless dehydrogenation to afford the corresponding N-heteroarenes and H-2 gas in o-xylene at 140 degrees C. The present protocol provides a convenient route to aromatic nitrogen-containing compounds and H-2 gas.
资助项目	National Natural Science Foundation of China[21871253] ; National Natural Science Foundation of China[21672209] ; National Basic Research Program of China[2015CB856600]
WOS关键词	BASE-FREE DEHYDROGENATION ; REVERSIBLE DEHYDROGENATION ; NITROGEN-HETEROCYCLES ; COMPLEXES BEARING ; HYDROGENATION ; ALCOHOLS ; CATALYST ; AMINES ; DERIVATIVES ; SUPEROXIDE
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000476040300001
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Basic Research Program of China ; National Basic Research Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Basic Research Program of China ; National Basic Research Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Basic Research Program of China ; National Basic Research Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Basic Research Program of China ; National Basic Research Program of China
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/173816]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Yu, Zhengkun
作者单位	1.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 354 Fenglin Rd, Shanghai 200032, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Inst Chem Henan Acad Sci, Zhengzhou 450002, Henan, Peoples R China
推荐引用方式 GB/T 7714	Liu, Tingting,Wu, Kaikai,Wang, Liandi,et al. Potassium tert-Butoxide-Promoted Acceptorless Dehydrogenation of N-Heterocycles[J]. ADVANCED SYNTHESIS & CATALYSIS,2019:8.
APA	Liu, Tingting,Wu, Kaikai,Wang, Liandi,&Yu, Zhengkun.(2019).Potassium tert-Butoxide-Promoted Acceptorless Dehydrogenation of N-Heterocycles.ADVANCED SYNTHESIS & CATALYSIS,8.
MLA	Liu, Tingting,et al."Potassium tert-Butoxide-Promoted Acceptorless Dehydrogenation of N-Heterocycles".ADVANCED SYNTHESIS & CATALYSIS (2019):8.