highlyefficientbasefreeaerobicoxidationofalcoholsovergoldnanoparticlessupportedonznocuomixedoxides

	highlyefficientbasefreeaerobicoxidationofalcoholsovergoldnanoparticlessupportedonznocuomixedoxides
	Wang Wei 2; Xie Yan 2; Zhang Shaohua 2; Liu Xing 2; Zhang Liyun 1; Zhang Bingsen 1; Harut Masatake 2; Huang Jiahui 2
刊名	chinesejournalofcatalysis
	2019-01-01
卷号	40 期号:12 页码:1924
ISSN号	1872-2067
英文摘要	The design and preparation of suitable supports are of great importance for gold catalysts to attain excellent catalytic performance for alcohol oxidation. In this work, we found that ZnO-CuO mixed oxides supported gold catalysts showed much better catalytic activity for base-free aerobic oxidation of benzyl alcohol than Au 0.7 Cu 0.3 O displayed the best catalytic performance. In addition, the Au 0.7 Cu 0.3 O catalyst could selectively catalyze the aerobic oxidation of a wide range of alcohols to produce the corresponding carbonyl compounds with high yields under mild conditions without base. Further characterizations indicated that the outstanding catalytic performance of Au 0.7 Cu 0.3 O was correlated with the small size of Au nanoparticles (NPs), good low-temperature reducibility, high concentration of surface oxygen species, and collaborative interaction between Au NPs and mixed oxide.
语种	英语
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/172234]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.中国科学院金属研究所 2.中国科学院大连化学物理研究所
推荐引用方式 GB/T 7714	Wang Wei,Xie Yan,Zhang Shaohua,et al. highlyefficientbasefreeaerobicoxidationofalcoholsovergoldnanoparticlessupportedonznocuomixedoxides[J]. chinesejournalofcatalysis,2019,40(12):1924.
APA	Wang Wei.,Xie Yan.,Zhang Shaohua.,Liu Xing.,Zhang Liyun.,...&Huang Jiahui.(2019).highlyefficientbasefreeaerobicoxidationofalcoholsovergoldnanoparticlessupportedonznocuomixedoxides.chinesejournalofcatalysis,40(12),1924.
MLA	Wang Wei,et al."highlyefficientbasefreeaerobicoxidationofalcoholsovergoldnanoparticlessupportedonznocuomixedoxides".chinesejournalofcatalysis 40.12(2019):1924.