Hydrogen-bonding directed reversal of enantioselectivity

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	Hydrogen-bonding directed reversal of enantioselectivity
	ZENG WEI ; CHEN GUOYING ; Zhou YG(周永贵) ; Li YX(李玉学)
刊名	J. Am. Chem. Soc.
	2007
卷号	129 期号:4 页码:750-751
ISSN号	0002-7863
其他题名	Hydrogen-bonding directed reversal of enantioselectivity
通讯作者	周永贵 ; 李玉学
英文摘要	A successful stereochemical reversal was achieved in AgOAc catalyzed [3+2] cycloaddition by the formation of hydrogen bonding between ligand and reactant. This strategy provides an efficient and convenient route to prepare both enantiomers of a chiral compound. DFT studies proposed a reasonable mechanism of the reversal of the enantioselectivity; hydrogen bonding changed the transition state. The strategy may provide some useful hints for ligand design.
学科主题	分析化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/ja067346f
语种	英语
WOS记录号	WOS:000243683800013
公开日期	2013-08-14
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/27689]
专题	上海有机化学研究所_上海有机化学研究所
推荐引用方式 GB/T 7714	ZENG WEI,CHEN GUOYING,Zhou YG,et al. Hydrogen-bonding directed reversal of enantioselectivity[J]. J. Am. Chem. Soc.,2007,129(4):750-751.
APA	ZENG WEI,CHEN GUOYING,周永贵,&李玉学.(2007).Hydrogen-bonding directed reversal of enantioselectivity.J. Am. Chem. Soc.,129(4),750-751.
MLA	ZENG WEI,et al."Hydrogen-bonding directed reversal of enantioselectivity".J. Am. Chem. Soc. 129.4(2007):750-751.