Post-annealing Effect on Microstructures and Thermoelectric Properties of Bi0.45Sb1.55Te3 Thin Films Deposited by Co-sputtering
Song, Junqiang; Chen, Xihong; Tang, Yunshan; Yao, Qin; Chen, Lidong
刊名JOURNAL OF ELECTRONIC MATERIALS
2012-11-01
卷号41期号:11页码:3068-3072
关键词Thermoelectric bismuth telluride sputtering thin film post-annealing
其他题名Post-annealing Effect on Microstructures and Thermoelectric Properties of Bi0.45Sb1.55Te3 Thin Films Deposited by Co-sputtering
通讯作者Chen, LD
英文摘要p-Type Bi0.45Sb1.55Te3 thermoelectric (TE) thin films have been prepared at room temperature by a magnetron cosputtering process. The effect of postannealing on the microstructure and TE properties of Bi0.45Sb1.55Te3 films has been investigated in the temperature range from room temperature to 350A degrees C. x-Ray diffraction analysis shows that the annealed films have polycrystalline rhombohedral crystal structure, and the average grain size increases from 36 nm to 64 nm with increasing annealing temperature from room temperature to 350A degrees C. Electron probe microanalysis shows that annealing above 250A degrees C can cause Te reevaporation, which induces porous thin films and dramatically affects electrical transport properties of the thin films. TE properties of the films have been investigated at room temperature. The hole concentration shows a trend from descent to ascent and has a minimum value at the annealing temperature of 200A degrees C, while the Seebeck coefficient shows an opposite trend and a maximum value of 245 mu V K-1. The electrical resistivity monotonically decreases from 19.8 m Omega cm to 1.4 m Omega cm with increasing annealing temperature. Correspondingly, a maximum value of power factor, 27.4 mu W K-2 cm(-1), was obtained at the annealing temperature of 250A degrees C.
学科主题无机非金属材料
WOS标题词Science & Technology ; Technology ; Physical Sciences
类目[WOS]Engineering, Electrical & Electronic ; Materials Science, Multidisciplinary ; Physics, Applied
研究领域[WOS]Engineering ; Materials Science ; Physics
关键词[WOS]FLASH EVAPORATION METHOD ; ANTISITE DEFECTS ; BULK ALLOYS ; FABRICATION ; PERFORMANCE ; DEVICES ; MERIT
收录类别SCI
语种英语
WOS记录号WOS:000309677200014
公开日期2013-07-19
内容类型期刊论文
源URL[http://ir.sic.ac.cn/handle/331005/3562]  
专题上海硅酸盐研究所_能量转换材料重点实验室_期刊论文
作者单位Chinese Acad Sci, Shanghai Inst Ceram, CAS Key Lab Mat Energy Convers, Shanghai 200050, Peoples R China
推荐引用方式
GB/T 7714
Song, Junqiang,Chen, Xihong,Tang, Yunshan,et al. Post-annealing Effect on Microstructures and Thermoelectric Properties of Bi0.45Sb1.55Te3 Thin Films Deposited by Co-sputtering[J]. JOURNAL OF ELECTRONIC MATERIALS,2012,41(11):3068-3072.
APA Song, Junqiang,Chen, Xihong,Tang, Yunshan,Yao, Qin,&Chen, Lidong.(2012).Post-annealing Effect on Microstructures and Thermoelectric Properties of Bi0.45Sb1.55Te3 Thin Films Deposited by Co-sputtering.JOURNAL OF ELECTRONIC MATERIALS,41(11),3068-3072.
MLA Song, Junqiang,et al."Post-annealing Effect on Microstructures and Thermoelectric Properties of Bi0.45Sb1.55Te3 Thin Films Deposited by Co-sputtering".JOURNAL OF ELECTRONIC MATERIALS 41.11(2012):3068-3072.
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