Solvothermal synthesis of luminescent Eu(BTC)(H2O)DMF hierarchical architectures | |
Xu BA ; Guo HL ; Wang S ; Li YY ; Zhang HJ ; Liu CG | |
刊名 | crystengcomm
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2012 | |
卷号 | 14期号:8页码:2914-2919 |
关键词 | METAL-ORGANIC FRAMEWORKS WATER-CHLOROFORM INTERFACE SELF-ASSEMBLED MONOLAYERS COORDINATION POLYMERS THIN-FILMS GROWTH PHOTOLUMINESCENCE CHEMISTRY Y2O3-EU3+ UNIFORM |
ISSN号 | 1466-8033 |
通讯作者 | guo hl |
中文摘要 | precise control over size and morphology of metal-organic frameworks (mofs) is challenging but important for extending these hybrid materials to many more advanced applications, in particular for nanotechnology and device integration. through exploring the reaction parameters during the synthesis of the eu-mofs, fascinating crystals morphologies, including urchin-like balls, straw-sheaf and nanocrystals have been obtained by solvothermal treatment. details of the formation mechanism of the resulting crystal morphology were investigated. all samples were characterized by x-ray powder diffraction, high resolution scanning electron microscopy, infrared spectroscopy and thermal gravimetry. the experimental results show that the formation of eu-mof is extremely sensitive to the synthesis conditions, hence resulting in different morphologies. these well-arranged architectures exhibit red emission corresponding to the d-5(0)-f-7(2) transition of the eu3+ ions under uv light excitation, and the lifetime is determined to be about 0.663 ms |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000301735400040 |
公开日期 | 2013-06-30 |
内容类型 | 期刊论文 |
源URL | [http://ir.ciac.jl.cn/handle/322003/48609] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Xu BA,Guo HL,Wang S,et al. Solvothermal synthesis of luminescent Eu(BTC)(H2O)DMF hierarchical architectures[J]. crystengcomm,2012,14(8):2914-2919. |
APA | Xu BA,Guo HL,Wang S,Li YY,Zhang HJ,&Liu CG.(2012).Solvothermal synthesis of luminescent Eu(BTC)(H2O)DMF hierarchical architectures.crystengcomm,14(8),2914-2919. |
MLA | Xu BA,et al."Solvothermal synthesis of luminescent Eu(BTC)(H2O)DMF hierarchical architectures".crystengcomm 14.8(2012):2914-2919. |
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