Controllable synthesis of carbon nanofiber supported Pd catalyst for formic acid electrooxidation

	Controllable synthesis of carbon nanofiber supported Pd catalyst for formic acid electrooxidation
	Qin YH ; Jia YB ; Jiang Y ; Niu DF ; Zhang XS ; Zhou XG ; Niu L ; Yuan WK
刊名	international journal of hydrogen energy
	2012
卷号	37 期号:9 页码:7373-7377
关键词	PALLADIUM NANOPARTICLES FUEL-CELL SIZE PARTICLES NANOTUBES OXIDATION PLATINUM METHANOL
ISSN号	0360-3199
通讯作者	zhang xs
中文摘要	carbon nanofiber (cnf) supported pd nanoparticles are synthesized with sodium citrate and sodium borohydride served as stabilizing agent and reducing agent, respectively. the size and distribution of the supported pd nanoparticles are controlled by adjusting the ph value of the synthesis solution. analyses of the obtained pd/cnf catalysts indicate that the supported pd nanoparticles become more uniform in size and the average particle size is decreased from 5.85 to 3.62 nm with ph value of the synthesis solution increasing from 3.2 to 6.0. however, the further increasing of the ph value to 6.5 leads to an increased particle size and the formation of pdo phase in the synthesized pd/cnf catalyst. the pd/cnf catalyst synthesized at the ph value of 6.0 exhibits superior catalytic activity and stability for formic acid electrooxidation due to its small particle size end uniform size distribution. copyright (c) 2012, hydrogen energy publications, llc. published by elsevier ltd. all rights reserved.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000305040200005
公开日期	2013-05-22
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/48185]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Qin YH,Jia YB,Jiang Y,et al. Controllable synthesis of carbon nanofiber supported Pd catalyst for formic acid electrooxidation[J]. international journal of hydrogen energy,2012,37(9):7373-7377.
APA	Qin YH.,Jia YB.,Jiang Y.,Niu DF.,Zhang XS.,...&Yuan WK.(2012).Controllable synthesis of carbon nanofiber supported Pd catalyst for formic acid electrooxidation.international journal of hydrogen energy,37(9),7373-7377.
MLA	Qin YH,et al."Controllable synthesis of carbon nanofiber supported Pd catalyst for formic acid electrooxidation".international journal of hydrogen energy 37.9(2012):7373-7377.