Versatile Reactivities of ansa-Heteroborabenzene Divalent Ytterbium Amide toward Alkali-Metal Salts and the Generation of Heterometallic Ytterbium-Alkali-Metal Boratabenzene Complexes

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	Versatile Reactivities of ansa-Heteroborabenzene Divalent Ytterbium Amide toward Alkali-Metal Salts and the Generation of Heterometallic Ytterbium-Alkali-Metal Boratabenzene Complexes
	Cui P(崔鹏) ; Chen YF(陈耀峰) ; Li GY(李光玉) ; Xia W(夏薇)
刊名	Organometallics
	2011
卷号	30 期号:7 页码:2012-2017
ISSN号	0276-7333
其他题名	含ansa型硼杂苯配体的二价镱的胺基配合物与碱金属盐的多重反应性能及含有镱-碱金属杂双金属的硼杂苯配合物的合成
通讯作者	陈耀峰
英文摘要	Reactions of the ansa-heteroborabenzene divalent ytterbium amide [C(5)H(5)BCH(2)(CH(3))(2)P -> BC(5)H(5)]YbN(SiMe(3))(2) (1) with alkali-metal salts (KC(5)Me(5), NaO(I)Pr, NaoAr, LiNHAr, LiN(SiMe(3))(2), LiNEt(2), and KCH(2)Ar) were studied. The reaction of 1 with KC(5)Me(5) caused a ligand displacement of neutral borabenzene by KC(5)Me(5) at the Yb ion to give a heterometallic Yb-K boratabenzene complex with a polymeric structure, while that with NaO(i)Pr caused a ligand displacement of the anionic amido ligand at the Yb ion by an isopropoxyl ligand to give a heterometallic Yb-Na boratabenzene complex with a polymeric structure. When LiNEt(2) or KCH(2)Ar was employed as the reagent, the [NEt(2)](-) or [CH(2)Ar](-) group underwent nucleophilic attack at the B atom on the neutral borabenzene to cause the disassociation of the P -> B coordination bond and the generation of new boratabenzene ligands.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/om200040z
语种	英语
WOS记录号	WOS:000289008700033
公开日期	2013-04-11
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/25341]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Cui P,Chen YF,Li GY,et al. Versatile Reactivities of ansa-Heteroborabenzene Divalent Ytterbium Amide toward Alkali-Metal Salts and the Generation of Heterometallic Ytterbium-Alkali-Metal Boratabenzene Complexes[J]. Organometallics,2011,30(7):2012-2017.
APA	崔鹏,陈耀峰,李光玉,&夏薇.(2011).Versatile Reactivities of ansa-Heteroborabenzene Divalent Ytterbium Amide toward Alkali-Metal Salts and the Generation of Heterometallic Ytterbium-Alkali-Metal Boratabenzene Complexes.Organometallics,30(7),2012-2017.
MLA	崔鹏,et al."Versatile Reactivities of ansa-Heteroborabenzene Divalent Ytterbium Amide toward Alkali-Metal Salts and the Generation of Heterometallic Ytterbium-Alkali-Metal Boratabenzene Complexes".Organometallics 30.7(2011):2012-2017.