Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. A novel tetrameric cluster of {(FeFe12III)-Fe-II(mu(3)-OH)(12)(mu(4)-PO4)(4)}(B-alpha-PW9O34)(4) (22- )

	Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. A novel tetrameric cluster of {(FeFe12III)-Fe-II(mu(3)-OH)(12)(mu(4)-PO4)(4)}(B-alpha-PW9O34)(4) (22- )
	J. W. Zhao ; J. Zhang ; S. T. Zheng ; G. Y. Yang
刊名	Inorganic Chemistry
	2007-12
卷号	46 期号:26 页码:10944-10946
关键词	magnetic-properties crystal-structure complexes polyoxotungstate heteropolyanions tungstophosphate polyoxoanions coordination anions wheel
ISSN号	0020-1669
中文摘要	A novel tetrameric cluster, (en H-2)(3.5)H-15[{(FeFeIII)-Fe-II](12)(mu(3)-OH)(12)(mu(4)-PO4)(4)}(B-alpha-PW9O34)(4)]center dot 83H(2)O (1; en = ethylenediamine), has been hydrothermally synthesized and characterized by IR, optical diffuse reflectance, thermogravimetric analysis, and single-crystal X-ray diffraction. The skeleton of 1 is composed of four tri-Fe-III-substituted [Fe-3(III)(mu(3)-OH)(3)(B-alpha-PW9O34)](3-) Keggin moieties fused together through a (Fe2O2)-O-II unit and four mu(4)-PO4 bridges, resulting in a unique tetramer with C-2 symmetry. Magnetic measurements indicate that 1 reveals the antiferromagnetic interactions between Fe-II and Fe-III centers.
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6911]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	J. W. Zhao,J. Zhang,S. T. Zheng,et al. Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. A novel tetrameric cluster of {(FeFe12III)-Fe-II(mu(3)-OH)(12)(mu(4)-PO4)(4)}(B-alpha-PW9O34)(4) (22- )[J]. Inorganic Chemistry,2007,46(26):10944-10946.
APA	J. W. Zhao,J. Zhang,S. T. Zheng,&G. Y. Yang.(2007).Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. A novel tetrameric cluster of {(FeFe12III)-Fe-II(mu(3)-OH)(12)(mu(4)-PO4)(4)}(B-alpha-PW9O34)(4) (22- ).Inorganic Chemistry,46(26),10944-10946.
MLA	J. W. Zhao,et al."Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. A novel tetrameric cluster of {(FeFe12III)-Fe-II(mu(3)-OH)(12)(mu(4)-PO4)(4)}(B-alpha-PW9O34)(4) (22- )".Inorganic Chemistry 46.26(2007):10944-10946.