Growth and characterization of nonlinear optical crystal Lu0.66La0.95SC2.39(BO3)(4)
W. Li ; L. X. Huang ; G. Zhang ; N. Ye
刊名Journal of Crystal Growth
2007-09
卷号307期号:2页码:405-409
关键词growth from high -temperature solutions single-crystal growth borates nonlinear optic materials rm(3)(bo3)(4) crystals
ISSN号0022-0248
中文摘要The new nonlinear optical (NLO) crystal LuxLayScz(BO3)(4) (X + Y + Z = 4) of trigonal phase has been synthesized by doping with Lu in monoclinic LaSC3(BO3)(4). Phase boundaries have been established in the determination of the x, y, z composition parameters that define the existence region of the trigonal huntite-type structure. From single-crystal X-ray diffraction measurements, the member Lu0.66La0.95SC2.39(BO3)(4) has been found to crystallize in space group R32 with cell dimensions a = 9.87420(1 0) and c = 8.0696 (7) angstrom. Large single crystals have been grown by a high-temperature top-seeding solution method. The UV absorption edge for polished pieces was found to be at a wavelength shorter than 200 nm. Sellmeier equations were established on the basis of the refractive indices measured by the method of auto-collimation. From modeling and optical measurements on powders, the (NLO) coefficient d(11) has been determined to be 1.3 pm/V. (c) 2007 Elsevier B.V. All rights reserved.
语种英语
公开日期2013-04-01
内容类型期刊论文
源URL[http://ir.fjirsm.ac.cn/handle/350002/6413]  
专题福建物质结构研究所_中科院福建物质结构研究所_期刊论文
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W. Li,L. X. Huang,G. Zhang,et al. Growth and characterization of nonlinear optical crystal Lu0.66La0.95SC2.39(BO3)(4)[J]. Journal of Crystal Growth,2007,307(2):405-409.
APA W. Li,L. X. Huang,G. Zhang,&N. Ye.(2007).Growth and characterization of nonlinear optical crystal Lu0.66La0.95SC2.39(BO3)(4).Journal of Crystal Growth,307(2),405-409.
MLA W. Li,et al."Growth and characterization of nonlinear optical crystal Lu0.66La0.95SC2.39(BO3)(4)".Journal of Crystal Growth 307.2(2007):405-409.
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