A series of cadmium(II) coordination polymers synthesized at different pH values

	A series of cadmium(II) coordination polymers synthesized at different pH values
	Z. G. Guo ; R. Cao ; X. J. Li ; D. Q. Yuan ; W. H. Bi ; X. D. Zhu ; Y. F. Li
刊名	European Journal of Inorganic Chemistry
	2007-02
期号	5 页码:742-748
关键词	cadmium polymers self-assembly photoluminescence metal-organic framework crystal-structures hydrothermal syntheses emission properties magnetic-properties selective binding trimesic acid ligands 3-(2-pyridyl)pyrazole terephthalate
ISSN号	1434-1948
中文摘要	A new family of cadmium(II) coordination polymers, {[Cd(Hbic)(2)center dot(H2O)(2)]center dot 2H(2)O}(n) (1), [Cd(Hbic)(2)](n) (2), [Cd(Hbic)(2)center dot (H2O)](n) (3), H(2)bic = 1H-benzimidazole-5-carboxylic acid, has been hydrothermally prepared by the assembly of Cd` with H(2)bic. A change in the pH values resulted in a series of compounds with different compositions and dimensionalities. Formed at the lowest pH, compound 1 has a two-dimensional supramolecular structure, which contains 1D chains ex- tended by hydrogen bonds. At a slightly higher pH, compound 2 is synthesized with a higher number of deprotonated carboxylate groups per cadmium atom. A further increase in the pH leads to 3D dinuclear compound 3 with yellow-green emitting fluorescence. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6279]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	Z. G. Guo,R. Cao,X. J. Li,et al. A series of cadmium(II) coordination polymers synthesized at different pH values[J]. European Journal of Inorganic Chemistry,2007(5):742-748.
APA	Z. G. Guo.,R. Cao.,X. J. Li.,D. Q. Yuan.,W. H. Bi.,...&Y. F. Li.(2007).A series of cadmium(II) coordination polymers synthesized at different pH values.European Journal of Inorganic Chemistry(5),742-748.
MLA	Z. G. Guo,et al."A series of cadmium(II) coordination polymers synthesized at different pH values".European Journal of Inorganic Chemistry .5(2007):742-748.