A pH-Sensitive Biopolymer-Based Superabsorbent Nanocomposite from Sodium Alginate and Attapulgite: Synthesis, Characterization, and Swelling Behaviors
Yang HX(杨会霞)1,2; Wang WB(王文波)1,3; Wang AQ(王爱勤)1
刊名Journal of Dispersion Science and Technology
2012
卷号33期号:8页码:1154-1162
关键词Attapulgite pH-sensitive polyvinylperrodone sodium alginate superabsorbent nanocomposite swelling
ISSN号0193-2691
通讯作者王爱勤
英文摘要Graft copolymerization reaction among sodium alginate (NaAlg), sodium acrylate (NaA), and nanoscale attapulgite (APT) was performed to fabricate a novel pH-sensitive NaAlg-g-PNaA/APT superabsorbent nanocomposite. FTIR spectra proved NaA monomers were grafted onto NaAlg backbone and APT participated in polymerization. FESEM, TEM, and TGA analyses revealed the better dispersion of APT fibrils in the matrix and the improved thermal stability. The swelling capacity and rate of the superabsorbent was clearly enhanced after introducing APT. The external salts and surfactants showed greater influence on the swelling behaviors. The nanocomposite exhibited reversible On-Off pH-sensitivity between pHs 2.0 and 7.4, and the intriguing pH-triggered deswelling behavior in various polyvinylperrodone (PVP) solutions was observed.
学科主题环境材料与生态化学
收录类别SCI
资助信息the National Natural Science Foundation of China (No. 20877077);the Science and Technology Support Project of Jiangsu Provincial Scence & Technology Department (No. BY2010012);the Open Fund of the Key Laboratory of Chemistry of Northwestern Plant Resources, Chinese Academy of Sciences (No. CNPR2010kfkt01)
语种英语
WOS记录号WOS:000307059800010
公开日期2013-03-24
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/2549]  
专题兰州化学物理研究所_环境材料与生态化学研究发展中心
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Xuyi Attapulgite Appl Technol, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing, Peoples R China
3.Chinese Acad Sci, Key Lab Chem NW Plant Resources, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Yang HX,Wang WB,Wang AQ. A pH-Sensitive Biopolymer-Based Superabsorbent Nanocomposite from Sodium Alginate and Attapulgite: Synthesis, Characterization, and Swelling Behaviors[J]. Journal of Dispersion Science and Technology,2012,33(8):1154-1162.
APA Yang HX,Wang WB,&Wang AQ.(2012).A pH-Sensitive Biopolymer-Based Superabsorbent Nanocomposite from Sodium Alginate and Attapulgite: Synthesis, Characterization, and Swelling Behaviors.Journal of Dispersion Science and Technology,33(8),1154-1162.
MLA Yang HX,et al."A pH-Sensitive Biopolymer-Based Superabsorbent Nanocomposite from Sodium Alginate and Attapulgite: Synthesis, Characterization, and Swelling Behaviors".Journal of Dispersion Science and Technology 33.8(2012):1154-1162.
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