Electrokinetic and Colloidal Properties of Homogenized and Unhomogenized Palygorskite in the Presence of Electrolytes
Xu JX(徐继香); Wang AQ(王爱勤)1
刊名Journal of Chemical and Engineering Data
2012
卷号57期号:5页码:1586-1593
ISSN号0021-9568
通讯作者王爱勤
英文摘要A series of palygorskite samples modified with electrolytes containing LiCl, NaCl, KCl, CsCl, MgCl2, CaCl2, AlCl3, and FeCl3 were prepared with the aid of high-pressure homogenization and mechanical stirring techniques. The changes of electrokinetic and colloidal properties of modified palygorskite were investigated in detail through the measurement of the zeta potential, yield stress, and sedimentation volume. The influences of charge, concentration, and type of ions on the surface potential of palygorskite were compared. The correlation between the zeta potential and the colloidal properties of obtained palygorskite was discussed. The homogenization process could favor the adsorption of ions onto palygorskite surface and enhance the colloidal properties of suspension. It was found that the 0.05 mol·kg–1 AlCl3 and FeCl3 reversed the surface charge of palygorskite from negative to positive. The yield stress measurements demonstrated that the association capacity of rods depended on the surface potential and interparticle interactions of palygorskite. A stable suspension was obtained when palygorskite was dispersed in MgCl2 solutions and homogenized at 30 MPa.
学科主题环境材料与生态化学
收录类别SCI
资助信息the Science and Technology Support Project of Jiangsu Provincial Sci. & Tech. Department (No. BY2010012);Jiangsu Provincial Joint Innovation and Research Funding of Enterprises, Colleges and Institutes-Prospective Cooperative Research Project (No. BY2011194)
语种英语
WOS记录号WOS:000303786200033
公开日期2013-03-24
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/2542]  
专题兰州化学物理研究所_环境材料与生态化学研究发展中心
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Xuyi Attapulgite Appl Technol, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
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Xu JX,Wang AQ. Electrokinetic and Colloidal Properties of Homogenized and Unhomogenized Palygorskite in the Presence of Electrolytes[J]. Journal of Chemical and Engineering Data,2012,57(5):1586-1593.
APA Xu JX,&Wang AQ.(2012).Electrokinetic and Colloidal Properties of Homogenized and Unhomogenized Palygorskite in the Presence of Electrolytes.Journal of Chemical and Engineering Data,57(5),1586-1593.
MLA Xu JX,et al."Electrokinetic and Colloidal Properties of Homogenized and Unhomogenized Palygorskite in the Presence of Electrolytes".Journal of Chemical and Engineering Data 57.5(2012):1586-1593.
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