Efficient Synthesis and Ring-Opening Reactions of Monofluorinated Epoxides Derived from alpha-Fluorosulfoximines

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	Efficient Synthesis and Ring-Opening Reactions of Monofluorinated Epoxides Derived from alpha-Fluorosulfoximines
	Zhang W(张伟) ; Hu JB(胡金波)
刊名	Adv. Synth. Catal.
	2010
卷号	352 期号:16 页码:2799-2804
ISSN号	1615-4150
其他题名	利用α-一氟亚砜亚胺制备一氟环氧乙烷衍生物以及后续开环转化
通讯作者	胡金波
英文摘要	Monofluorinated epoxides were successfully prepared through the O-cyclization reaction between alpha-fluorosulfoximines and ketones. The obtained fluoroepoxides were found to readily undergo an interesting ring-opening process (involving both a C-F bond cleavage and another C-F bond formation) in the presence of titanium tetrafluoride or pyridinium poly(hydrogen fluoride) to afford alpha-fluorinated ketones. The later process constitutes a formal catalytic 1,2-fluorine shift reaction.
学科主题	氟化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/adsc.201000499
语种	英语
WOS记录号	WOS:000284004200015
公开日期	2013-03-11
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/24065]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
推荐引用方式 GB/T 7714	Zhang W,Hu JB. Efficient Synthesis and Ring-Opening Reactions of Monofluorinated Epoxides Derived from alpha-Fluorosulfoximines[J]. Adv. Synth. Catal.,2010,352(16):2799-2804.
APA	张伟,&胡金波.(2010).Efficient Synthesis and Ring-Opening Reactions of Monofluorinated Epoxides Derived from alpha-Fluorosulfoximines.Adv. Synth. Catal.,352(16),2799-2804.
MLA	张伟,et al."Efficient Synthesis and Ring-Opening Reactions of Monofluorinated Epoxides Derived from alpha-Fluorosulfoximines".Adv. Synth. Catal. 352.16(2010):2799-2804.