Gold(I)-Catalyzed Tandem C-H and C-C Activation (Cleavage)

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	Gold(I)-Catalyzed Tandem C-H and C-C Activation (Cleavage)
	Jiang M(蒋敏) ; Lu JM(陆建梅) ; Shi M(施敏) ; Li YX(李玉学)
刊名	Org. Lett.
	2010
卷号	12 期号:1 页码:116-119
其他题名	金催化的碳-碳和碳-氢键的串联断裂反应
通讯作者	施敏 ; 李玉学
英文摘要	(Cyclopropylidenecyclohexyl)benzene derivatives, a kind of methylenecyclopropane (MCP) containing a cyclohexyl group, can undergo an Interesting tandem intramolecular C-H and C-C bond activation through dehydrogenated rearrangement in the presence of AuPPh3Cl/AgOTf by transferring three hydrogen atoms from cyclohexane to cyclopropane, affording the corresponding biaryl derivatives in moderate to good yields. The reaction mechanism has also been carefully investigated by deuterium labeling experiments and DFT calculations.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/ol902593f
语种	英语
WOS记录号	WOS:000272937200030
公开日期	2013-01-09
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/10396]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Jiang M,Lu JM,Shi M,et al. Gold(I)-Catalyzed Tandem C-H and C-C Activation (Cleavage)[J]. Org. Lett.,2010,12(1):116-119.
APA	Jiang M,Lu JM,Shi M,&Li YX.(2010).Gold(I)-Catalyzed Tandem C-H and C-C Activation (Cleavage).Org. Lett.,12(1),116-119.
MLA	Jiang M,et al."Gold(I)-Catalyzed Tandem C-H and C-C Activation (Cleavage)".Org. Lett. 12.1(2010):116-119.