Catalytic Enantioselective Arylation of N-Tosylarylimines with Arylboronic Acids Using C-2-Symmetric Cationic N-Heterocyclic Carbene Pd2+ Diaquo Complexes

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	Catalytic Enantioselective Arylation of N-Tosylarylimines with Arylboronic Acids Using C-2-Symmetric Cationic N-Heterocyclic Carbene Pd2+ Diaquo Complexes
	Ma GN(马光宁) ; Zhang T(张涛) ; Shi M(施敏)
刊名	Org. Lett.
	2009
卷号	11 期号:4 页码:875-878
其他题名	氮杂卡宾金属阳离子钯催化的芳基硼酸和磺酰亚胺的不对称加成反应
通讯作者	施敏
英文摘要	The asymmetric arylation of N-tosylimines with arylboronic acids was realized by using chiral cationic C-2-symmetric N-heterocyclic carbene (NHC) Pd2+ diaquo complex 5b as the catalyst in combination with 1.0 equiv of K3PO4 center dot 3H(2)O in THF at 4 degrees C in the presence of powdered 4 angstrom MS to afford the corresponding adducts in excellent yields (up to 99%) and good to high enantioselectivities (up to 94% ee).
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/ol802861s
语种	英语
WOS记录号	WOS:000263299000023
公开日期	2013-01-09
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/10314]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Ma GN,Zhang T,Shi M. Catalytic Enantioselective Arylation of N-Tosylarylimines with Arylboronic Acids Using C-2-Symmetric Cationic N-Heterocyclic Carbene Pd2+ Diaquo Complexes[J]. Org. Lett.,2009,11(4):875-878.
APA	Ma GN,Zhang T,&Shi M.(2009).Catalytic Enantioselective Arylation of N-Tosylarylimines with Arylboronic Acids Using C-2-Symmetric Cationic N-Heterocyclic Carbene Pd2+ Diaquo Complexes.Org. Lett.,11(4),875-878.
MLA	Ma GN,et al."Catalytic Enantioselective Arylation of N-Tosylarylimines with Arylboronic Acids Using C-2-Symmetric Cationic N-Heterocyclic Carbene Pd2+ Diaquo Complexes".Org. Lett. 11.4(2009):875-878.